Synthetic and Mechanistic Studies on the Homogeneous Catalysis of Transition Metal Complexes

过渡金属配合物的均相催化合成及机理研究

• 批准号: 9400808
• 负责人: Iwao Ojima
• 金额: $ 33.2万
• 依托单位: SUNY at Stony Brook
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1994
• 资助国家: 美国
• 起止时间: 1994-08-01 至 1997-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9400808&HistoricalAwards=false
• 关键词: Synthetic; Mechanistic; Studies; Homogeneous; Catalysis

9400808 Ojima The focus of this research is the investigation of the Rh and Rh-Co complex promoted silylcarbocyclization (SiCAC) reactions of enynes, alkynals and diynes. The SiCAC process will be examined for scope and limitation, synthetic application and mechanism. Mechanistic studies will be carried out using labeling experiments. %%% With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Iwao Ojima of the Department of Chemistry at SUNY, Stony Brook. Professor Ojima will focus his work on developing new and efficient homogeneous catalytic reactions that will provide useful synthetic methods for the preparation of organosilicon compounds. ***

9400808 Ojima这项研究的重点是对RH和RH-CO复合物的研究促进了恩尼斯，藻类和Diynes的甲硅烷基钙化（SICAC）反应。 将检查SICAC过程的范围和限制，合成应用和机制。 机械研究将使用标签实验进行。 合成有机计划凭借这一续签奖，支持Stony Brook Suny化学系的Iwao Ojima博士的研究。 Ojima教授将把他的工作集中在开发新的，有效的均质催化反应上，这些反应将为有机硅化合物的制备提供有用的合成方法。 ***