One coordinate carbon and boron: Universal progenitor ligands

一配位碳和硼：通用祖配体

• 批准号: DP1093516
• 负责人: Prof Anthony Hill
• 金额: $ 33.39万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2010
• 资助国家: 澳大利亚
• 起止时间: 2010-01-01 至 2013-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP1093516
• 关键词: coordinate; carbon; boron; Universal; progenitor

Compounds with bonds between metals and carbon (organometallic chemistry) underpin innumerable important industrial processes from fine chemicals to bulk agrochemical and polymer synthesis. Yet the simplest example, a single atom of carbon bound to a metal has only recently been discovered and is poorly understood. Australia's fledgling boron fine chemicals industry similarly benefits from metal-based processes. However, compounds with a single boron atom bound to a metal remain unknown. This proposal addresses metal-carbon and metal-boron chemistry from the most basic perspective, that of a single atom of boron or carbon, including the development of novel synthetic approaches and skills for the characterisation of such curious species.

金属和碳（有机金属化学）之间具有键合的化合物是无数重要的工业过程，从精细化学物质到大量的农业化学和聚合物合成。然而，最简单的例子是，最近才发现了与金属结合的单个碳原子，并且知之甚少。澳大利亚刚起步的硼精制化学品同样从金属工艺中受益。但是，与金属结合的单个硼原子的化合物仍然未知。该提议从最基本的角度（硼或碳的单个原子）来解决金属 - 碳和金属 - 波龙化学，包括开发新型的合成方法和以表征这种好奇物种的技能。