Metallaboratranes: Soft Scorpionates and Masked Metal Bases

Metallaboratranes：软蝎子酸盐和掩蔽金属碱

• 批准号: DP0342701
• 负责人: Prof Anthony Hill
• 金额: $ 26.15万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2003
• 资助国家: 澳大利亚
• 起止时间: 2003-01-01 至 2006-06-30
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0342701
• 关键词: Metallaboratranes; Soft; Scorpionates; Masked; Metal

All molecular metal compounds involve a metal surrounded by a group of electron donors (?ligands?). The design and manipulation of these ligand sets and their interactions with metals (?coordination chemistry?) underpins ALL applications of metals, be they in biological, pharmaceutical, materials or industrial applications. This proposal addresses the diametric opposite - the role-reversal wherein a metal centre acts as an electron donor to a ligand. This rare situation has only recently been firmly established in this research group, but promises to be part of a wider new coordination chemistry, the limits of which will be pursued in the proposed work.

所有分子金属化合物都涉及被一组电子供体（“配体”）包围的金属。这些配体组的设计和操作及其与金属的相互作用（“配位化学”）支撑着金属的所有应用，无论是在生物、制药、材料还是工业应用中。该提议解决了截然相反的问题——角色逆转，其中金属中心充当配体的电子供体。这种罕见的情况最近才在该研究小组中得到牢固确立，但有望成为更广泛的新配位化学的一部分，其局限性将在拟议的工作中得到解决。