Boryl Pincers and Beyond: Taming Borometallic Chemistry

硼基钳及其他：驯服硼金属化学

• 批准号: DP200101222
• 负责人: Prof Anthony Hill
• 金额: $ 29.49万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2020
• 资助国家: 澳大利亚
• 起止时间: 2020-06-01 至 2023-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP200101222
• 关键词: Boryl; Pincers; Beyond; Taming; Borometallic

Industrial applications of coordination complexes in catalysis reduce energy input and environmental impact but almost exclusively involve classical donors such as nitrogen, oxygen, sulfur and phosphorus. Boron, whilst prevalent and environmentally benign, is under-utilised in such applications, in part due to the high reactivity of the metal boron bond. This research will seek to tame and then exploit the unique features of boron within pincer ligand frameworks in metal coordination complexes, with particular attention focusing on, but not limited to catalytic alkyne metathesis.

配位络合物在催化中的工业应用减少了能量输入和环境影响，但几乎完全涉及氮、氧、硫和磷等经典供体。硼虽然普遍存在且对环境无害，但在此类应用中并未得到充分利用，部分原因是金属硼键的高反应性。 这项研究将寻求驯服并利用金属配位配合物中钳形配体框架内硼的独特特征，特别关注但不限于催化炔烃复分解。