Electron transfer in hydrogen bonded metal-organic materials.

氢键金属有机材料中的电子转移。

• 批准号: 2447951
• 金额: --
• 依托单位: University of Huddersfield
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2020
• 资助国家: 英国
• 起止时间: 2020 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-2447951
• 关键词: Electron; transfer; hydrogen; bonded; metal

Hydrogen bonds are non-covalent interactions, but they can be relatively strong. The directionality of the hydrogen bond makes it suitable for the design of self-assembled supramolecular architectures, which can be easier to process than materials with covalent interactions. Recent studies have shown that charge transport through hydrogen bonds can be as efficient as through pi-bonds. This project will develop self-assembled metal-organic hydrogen bonded materials that have interesting charge transport properties, which incorporate metal-metal quadruple bonds. The designed synthesis of hydrogen bonded conductive compounds is likely to lead to a new class of electro-active hybrid materials.

氢键是非共价相互作用的，但它们可能相对较强。氢键的方向性使其适合于自组装超分子体系结构的设计，这比具有共价相互作用的材料更容易处理。最近的研究表明，通过氢键的电荷运输可以像通过PI键一样有效。该项目将开发自组装的金属氢键材料，具有有趣的电荷传输特性，其中包含金属金属四键键。设计的氢键导电化合物的合成可能会导致一类新的电活性杂种材料。