Development of New Synthetic Methods for Biaryl Compounds Using Ring-Closing Metathesis
利用闭环复分解开发联芳基化合物的新合成方法
基本信息
- 批准号:22550029
- 负责人:
- 金额:$ 2.91万
- 依托单位:
- 依托单位国家:日本
- 项目类别:Grant-in-Aid for Scientific Research (C)
- 财政年份:2010
- 资助国家:日本
- 起止时间:2010 至 2012
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Biaryl compounds constitute a class of compounds employed in manyresearch fields. Therefore, the development of flexible synthetic methods for these compounds continuesto be an active area of research. The most common method for the preparation of biaryl compounds isthe transition-metal-catalyzed cross-coupling reaction between aryl halides and aryl metal reagents. Thesuccess of this powerful method, however, essentially depends upon the availability of the two couplingpartners. In this study, we developed a new synthetic approach to biaryl compounds from easilyprepared acyclic building blocks. The direct construction of aromatic rings using theRCEM/RCM/elimination sequence provides unique products without the formation of inseparable regioisomers.
联芳基化合物构成一类用于许多研究领域的化合物。因此,开发这些化合物的灵活合成方法仍然是一个活跃的研究领域。制备联芳基化合物最常用的方法是过渡金属催化的芳基卤化物与芳基金属试剂之间的交叉偶联反应。然而,这种强大方法的成功主要取决于两个耦合伙伴的可用性。在这项研究中,我们开发了一种从易于制备的无环结构单元合成联芳基化合物的新方法。使用RCEM/RCM/消除序列直接构建芳环提供了独特的产物,而不会形成不可分离的区域异构体。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Construction of Carbocyclic Ring of Indoles Using Ruthenium-Catalyzed Ring-Closing Olefin Metathesis Org
钌催化闭环烯烃复分解有机物构建吲哚碳环
- DOI:10.1021/ol201510u
- 发表时间:2011
- 期刊:
- 影响因子:0
- 作者:Kazuhiro Yoshida; Kazushi Hayashi;Akira Yanagisawa
- 通讯作者:Akira Yanagisawa
Construction of Carbocyclic Ring of Indoles Using Ruthenium-Catalyzed Ring-Closing Olefin Metathesis
钌催化闭环烯烃复分解反应构建吲哚碳环
- DOI:
- 发表时间:2011
- 期刊:
- 影响因子:0
- 作者:Kazuhiro Yoshida
- 通讯作者:Kazuhiro Yoshida
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YOSHIDA Kazuhiro其他文献
Influence of monomer type, plasticizer content, and powder/liquid ratio on setting characteristics of acrylic permanent soft denture liners based on poly(ethyl methacrylate/butyl methacrylate) and acetyl tributyl citrate
单体类型、增塑剂含量和粉/液比对基于聚甲基丙烯酸乙酯/甲基丙烯酸丁酯和乙酰柠檬酸三丁酯的丙烯酸永久软义齿衬垫的凝固特性的影响
- DOI:
10.4012/dmj.2020-319 - 发表时间:
2021 - 期刊:
- 影响因子:2.5
- 作者:
MORI Tomoyasu;TAKASE Kazuma;YOSHIDA Kazuhiro;OKAZAKI Hitomi;MURATA Hiroshi - 通讯作者:
MURATA Hiroshi
The Thesis That Prince Shotoku Did Not Exist
圣德太子不存在的论点
- DOI:
- 发表时间:
2006 - 期刊:
- 影响因子:0
- 作者:
YOSHIDA Kazuhiro - 通讯作者:
YOSHIDA Kazuhiro
Influence of monomer type, plasticizer content, and powder/liquid ratio on setting characteristics of acrylic permanent soft denture liners based on poly(ethyl methacrylate/butyl methacrylate) and acetyl tributyl citrate
单体类型、增塑剂含量和粉/液比对基于聚甲基丙烯酸乙酯/甲基丙烯酸丁酯和乙酰柠檬酸三丁酯的丙烯酸永久软义齿衬垫的凝固特性的影响
- DOI:
10.4012/dmj.2020-319 - 发表时间:
2021 - 期刊:
- 影响因子:2.5
- 作者:
MORI Tomoyasu;TAKASE Kazuma;YOSHIDA Kazuhiro;OKAZAKI Hitomi;MURATA Hiroshi - 通讯作者:
MURATA Hiroshi
YOSHIDA Kazuhiro的其他文献
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{{ truncateString('YOSHIDA Kazuhiro', 18)}}的其他基金
Practical Synthesis of Asymmetric Pyridine Catalysts Using Ring-closing Approach
使用闭环方法实际合成不对称吡啶催化剂
- 批准号:
15K05494 - 财政年份:2015
- 资助金额:
$ 2.91万 - 项目类别:
Grant-in-Aid for Scientific Research (C)
Development of hard reline resins with high durability
开发出高耐久性的硬质衬里树脂
- 批准号:
25861856 - 财政年份:2013
- 资助金额:
$ 2.91万 - 项目类别:
Grant-in-Aid for Young Scientists (B)
Synthesis of Condensed Aromatic Compounds Using Ring-Closing Metathesis
利用闭环复分解合成稠合芳香族化合物
- 批准号:
25810058 - 财政年份:2013
- 资助金额:
$ 2.91万 - 项目类别:
Grant-in-Aid for Young Scientists (B)
Development of micro actuation systems using ac electroosmotic flows
使用交流电渗流开发微驱动系统
- 批准号:
23360073 - 财政年份:2011
- 资助金额:
$ 2.91万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Development of Cord Type Actuator with Shape Adaptation Capabilityfor Advanced Endoscopes
开发具有形状适应能力的高级内窥镜绳式执行器
- 批准号:
22656042 - 财政年份:2010
- 资助金额:
$ 2.91万 - 项目类别:
Grant-in-Aid for Challenging Exploratory Research
Development of Practical Synthetic Methods for Substituted Aromatic Compounds
取代芳香族化合物实用合成方法的发展
- 批准号:
20750069 - 财政年份:2008
- 资助金额:
$ 2.91万 - 项目类别:
Grant-in-Aid for Young Scientists (B)
Fabrication of Advanced In-Pipe Working Micromachine Using Electro-Rheological Fluids
使用电流变流体制造先进的管内工作微型机器
- 批准号:
10555058 - 财政年份:1998
- 资助金额:
$ 2.91万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Molecular cloning of the cancer metastasis associated gene and its clinical applications.
癌症转移相关基因的分子克隆及其临床应用。
- 批准号:
10671117 - 财政年份:1998
- 资助金额:
$ 2.91万 - 项目类别:
Grant-in-Aid for Scientific Research (C)
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