Electron-transfer Control on Molecular-Functional Conductor Surfaces and Its Application

分子功能导体表面的电子转移控制及其应用

• 批准号: 07305038
• 负责人: OYAMA Noboru
• 金额: $ 7.94万
• 依托单位: Tokyo University of Agriculture and Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 1995
• 资助国家: 日本
• 起止时间: 1995 至 1997
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07305038/
• 关键词: Molecular Function; Conductor Surface; Electron-transfer Control; Electrode Reaction; Surface Evaluation Method; Electroactive; Electrochemical Sensor; Battery Material; 電子移動反応; 界面修飾; 触媒作用; センシング; マイクロ電極; エネルギー変換; 電気化学; 修飾電極; 電子移動

This research project has focused on electrodes functionalized with ad-atoms and electroactive molecules, such as transition metals, redox polymers, conducting films LB films, self-assembled films, etc. Emphasis was placed on those topics dealing with the creation of new electrode surface, the synthesis of new electroactive materials and novel characterization methods associated with chemically modified electrode surfaces and the analysis and contro of electron transfer and mass transport processes within the films. The project demonstrated the performance results of these new materials and electrode surfaces in batteries, sensors, and other, electronic devices.

该研究项目的重点是用ad原子和电活性分子功能化的电极，例如过渡金属、氧化还原聚合物、导电膜LB膜、自组装膜等。重点放在涉及新电极表面创建的主题上、新型电活性材料的合成和与化学改性电极表面相关的新型表征方法以及薄膜内电子转移和质量传输过程的分析和控制。该项目展示了这些新材料和电极表面在电池、传感器和其他电子设备中的性能结果。

项目成果

Isao Taniguchi: ""Electrochemical Study of Biological Functions of Particular Evolutionaly Conserved Amino Acid Residues Using Mutated Molecules of Maize Ferredoxin"" Cem.Lett.1997. 929-930 (1997)

Isao Taniguchi：“使用玉米铁氧还蛋白突变分子对特定进化保守氨基酸残基的生物学功能进行电化学研究”Cem.Lett.1997。

大澤雅俊: "In Situ Real-Time Surface-Enhanced Infraed Study of Electrochemical Reactions" Applied Spectroscopy. 51・4(印刷中). (1997)

Masatoshi Osawa：“电化学反应的原位实时表面增强红外研究”51・4（出版中）。

藤嶋昭: "Molecular-Level Design of a Photoinduced Magnetic Spin Coupling System : Nickel Nitroprusside" The Jounal of Physical Chemistry. 47. 18289-18291 (1996)

Akira Fujishima：“光致磁自旋耦合系统的分子级设计：硝基普镍”《物理化学杂志》47。18289-18291 (1996)。

Geyu Lu: "High-Temperature for NO and NO_2 Based on Stabilized Zirconia and Spinel-Type Oxide Electrodes" Journal of Material Chemistry. 7. 1445-1449 (1997)

陆歌宇：“基于稳定氧化锆和尖晶石型氧化物电极的高温NO和NO_2”材料化学杂志。

Kohei Uosaki: "Electrochemical Epitaxial Growth of a Pt(111)Phase on an Au(111)Electrode" Journal of Physical Chemistry B. 101. 7566-7572 (1997)

Kohei Uosaki：“Pt(111)相在 Au(111) 电极上的电化学外延生长” 物理化学杂志 B. 101. 7566-7572 (1997)