Cyanogels: A Coordination Polymer Based System for the Synthesis of Solid-State Materials Via Sol-Gel Processing

氰凝胶：一种基于配位聚合物的系统，用于通过溶胶-凝胶加工合成固态材料

• 批准号: 0079169
• 负责人: Andrew Bocarsly
• 金额: $ 39.5万
• 依托单位: Princeton University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2000
• 资助国家: 美国
• 起止时间: 2000-08-15 至 2003-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0079169&HistoricalAwards=false
• 关键词: Cyanogels; Coordination; Polymer; Based; System

This award to Professor Andrew Bocarsly of Princeton University is a renewal of an earlier award and is supported by the Advanced Materials and Processing Program in the Chemistry Division. The focus of the award will be to develop the chemistry of cyanogels based on multi-metal cyanides prepared by sol-gel processing. Systemic development of cyanogel chemistry, their characterization for catalysis, and low temperature processing of them in ceramics, semiconductors and coatings for electrodes will be part of this award. Studies with cyanogel to absorb and preconcentrate carbon dioxide and finally to reduce to methanol will be carried out under this award. Also, multimetal cyanogel will be evaluated as electrocatalysts at low temperatures for combinatorial chemistry. Teaching and training of students in materials science at all levels from high school to graduate school including teachers from high school are parts of the award. Cyanogels prepared from multi-metal cyanides by sol-gel processing will be characterized for functional properties and for applications in catalysis, and for the preparation of ceramics, semiconductors and coatings for electrodes. Use of cyanogels for the absorption and preconcentration of carbon dioxide and its reduction of methanol, will have a lasting improvement in the environment in general, and in the energy sector in particular. In addition, the research program will provide a rich multidisciplinary education and training opportunity in materials chemistry to postdoctoral and graduate students, and students and teachers from high schools.

该奖项授予普林斯顿大学的安德鲁博卡利教授，是较早奖项的续签，并得到了化学部的高级材料和加工计划的支持。 该奖项的重点是基于通过溶胶 - 凝胶加工制备的多金属氰化物来开发蓝凝的化学。 该奖项的一部分将成为蓝凝化学的系统性开发，催化性的催化作用以及它们在陶瓷，半导体和电极涂料中的低温处理将是该奖项的一部分。 根据该奖项，对氰共凝凝胶的吸收和二氧化碳二氧化碳的研究将根据该奖项进行。 此外，在低温下，将评估多含氧凝胶作为组合化学的电催化剂。 该奖项的一部分是从高中到研究生院（包括高中教师）的各级材料科学的学生的教学和培训。通过溶胶 - 凝胶加工从多金属氰化物制备的氰凝结将以功能特性和催化中的应用以及用于电极的陶瓷，半导体和涂层的准备。使用蓝凝鼠凝胶来吸收和预浓缩二氧化碳及其减少甲醇，将在整个环境，尤其是能源部门的环境中持久改善。此外，该研究计划将为博士后和研究生以及高中的学生和老师提供丰富的多学科教育和材料化学培训机会。