Dynamics of Heterogeneous Reactions

非均相反应动力学

• 批准号: 9619190
• 负责人: Andrew Bocarsly
• 金额: $ 55.5万
• 依托单位: Princeton University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1997
• 资助国家: 美国
• 起止时间: 1997-03-01 至 2001-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9619190&HistoricalAwards=false
• 关键词: Dynamics; Heterogeneous; Reactions

This project, having long-term technological relevance, is supported in the Analytical and Surface Chemistry Program, and focusses on the study of heterogeneous reaction dynamics. Professor Andrew B. Bocarsly and his students at Princeton University will use molecular beams, surface spectroscopic and microscopic methods, and flow reactor studies to characterize the reactions so that models for these processes can be developed. Catalytic decomposition and oxidation reactions will be studied in detail. Many technologically important processes occur between gas and liquid phase reactants and solid surfaces. These heterogeneous reactions can increase the efficiency of important industrial processes and be used to limit amounts of undesirable constituents present in effluents from many common processes. Professor Bocarsly and his students at Princeton University will study reactions involving carbon monoxide and nitrogen oxides as well as processes for preparing solid surfaces that have desired catalytic properties.

该项目具有长期技术相关性，在分析和表面化学计划中得到了支持，并专注于研究异质反应动力学的研究。 Andrew B. Bocarsly教授及其普林斯顿大学的学生将使用分子束，表面光谱和微观方法，以及流动反应器研究以表征反应，以便可以开发出这些过程的模型。 将详细研究催化分解和氧化反应。 气体和液相反应物和固体表面之间发生了许多技术上重要的过程。 这些异质反应可以提高重要的工业过程的效率，并用于限制许多常见过程中废水中存在的不良成分的数量。 Bocarsly教授和他的普林斯顿大学的学生将研究涉及一氧化碳和氮氧化物的反应，以及准备所需催化特性的固体表面的过程。