Isotopic properties of carbonate minerals: searching for hidden environmental changes and their origins

碳酸盐矿物的同位素特性：寻找隐藏的环境变化及其起源

• 批准号: 386188-2010
• 负责人: Kim, SangTae
• 金额: $ 1.97万
• 依托单位: McMaster University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2013
• 资助国家: 加拿大
• 起止时间: 2013-01-01 至 2014-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=528768
• 关键词: Isotopic; properties; carbonate; minerals; searching

The goal of my proposed research program is to gain a deeper understanding of the isotopic properties of divalent metal carbonates (1) to provide the scientific community with versatile environmental proxies that allow us to trace current and past environmental changes and (2) to establish reliable biosignature-indicators that can be used to differentiate carbonates of various origins (primary vs. secondary, inorganic vs. biogenic). For several decades, isotopic properties of natural carbonates have been extensively used to reconstruct past climate variations. Nevertheless, most studies focused on the "oxygen" and "carbon" isotope properties of calcium carbonates because of the well-established analytical techniques and the ubiquity of the minerals. The isotopic properties of other elements in calcium carbonates and those of other divalent metal carbonates have attracted far less attention and thus have not been thoroughly investigated. For this reason, I am proposing to investigate the isotopic systematics of non-traditional stable isotopes (e.g., B, Ca, Li, and Fe) as well as clumped isotopes (e.g., Ca13C18O16O2) in a variety of divalent metal carbonate-water systems. The first objective of my research program is to quantify the "equilibrium" isotope fractionations of multiple stable isotopes in the carbonate-water system as a function of temperature and solution chemistry. For example, the Ca-C-O-B-(Li) isotope systematics in the calcite-seawater system will be characterized to develop new multi-element environmental proxies that will allow us to reconstruct paleo-climate, pH, or ocean chemistry. The second objective is to identify biogenic "non-equilibrium" isotope effects of multiple isotopes by disentangling these vital effects from the abiogenic "non-equilibrium" isotope effects on the basis of multi-dimensional stable isotope data arrays collected from a series of laboratory experiments conducted under various experimental conditions. The outcomes of the research program will establish reliable datasets for inorganic systems that will serve to interpret traditional and non-traditional stable isotope compositions of terrestrial and extraterrestrial carbonate specimens.

我提出的研究计划的目标是更深入地了解二价金属碳酸盐的同位素性质（1）为科学界提供通用的环境代理，使我们能够追踪当前和过去的环境变化，以及（2）建立可靠的环境代理生物特征指标，可用于区分各种来源的碳酸盐（原生碳酸盐与次生碳酸盐、无机碳酸盐与生物碳酸盐）。 几十年来，天然碳酸盐的同位素特性已被广泛用于重建过去的气候变化。 尽管如此，由于成熟的分析技术和矿物质的普遍存在，大多数研究都集中在碳酸钙的“氧”和“碳”同位素特性上。 碳酸钙中其他元素和其他二价金属碳酸盐的同位素性质引起的关注要少得多，因此尚未得到彻底研究。 因此，我建议研究各种二价金属碳酸盐-水系统中的非传统稳定同位素（例如 B、Ca、Li 和 Fe）以及簇同位素（例如 Ca13C18O16O2）的同位素系统学。 我的研究计划的第一个目标是量化碳酸盐-水系统中多种稳定同位素的“平衡”同位素分馏作为温度和溶液化学的函数。 例如，方解石-海水系统中的 Ca-C-O-B-(Li) 同位素系统将被表征，以开发新的多元素环境代理，使我们能够重建古气候、pH 值或海洋化学。 第二个目标是根据从一系列实验室实验收集的多维稳定同位素数据阵列，将这些重要效应与非生物“非平衡”同位素效应分开，从而识别多种同位素的生物“非平衡”同位素效应在各种实验条件下进行。 该研究计划的成果将为无机系统建立可靠的数据集，用于解释陆地和地外碳酸盐样本的传统​​和非传统稳定同位素组成。