Boron-Boron Exchange Catalysis

硼-硼交换催化

• 批准号: 2112603
• 金额: --
• 依托单位: University of Edinburgh
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2018
• 资助国家: 英国
• 起止时间: 2018 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-2112603
• 关键词: Boron; Exchange; Catalysis

This PhD studentship will develop and demonstrate a new catalysis manifold based on main group elements. The high reactivity of main group catalysts will be combined with the stability of a boronic ester. The main group catalyst will be used to functionalise the substrate and a boronic ester will be used to give a bench-stable product. The potential of this sustainable catalytic paradigm will be demonstrated in widely used and industrially important transformations. Key objects: Synthesis, characterise and apply new main group catalysts in synthetically and industrially relevant transformations. Key techniques: Organic and inorganic synthesis, reaction optimisation, catalyst development and improvement, compound characterisation. Novel combination of physical organic and inorganic reaction monitoring to catalyst mechanism and fundamental reactivity.

该博士生奖学金将开发并展示一种基于主族元素的新催化流形。主族催化剂的高反应活性与硼酸酯的稳定性相结合。主族催化剂将用于使底物官能化，硼酸酯将用于产生实验室稳定的产物。这种可持续催化范式的潜力将在广泛使用和工业上重要的转化中得到证明。主要目标：在合成和工业相关转化中合成、表征和应用新的主族催化剂。关键技术：有机和无机合成、反应优化、催化剂开发和改进、化合物表征。物理有机和无机反应监测的新颖组合，以监测催化剂机理和基本反应性。