NMR SPECTROMETER

核磁共振波谱仪

• 批准号: 3522019
• 负责人: EDWIN VEDEJS
• 金额: $ 10.1万
• 依托单位: UNIVERSITY OF WISCONSIN-MADISON
• 依托单位国家: 美国
• 财政年份: 1993
• 资助国家: 美国
• 起止时间: 1993-09-01 至 1994-08-31
• 项目状态: 已结题
• 来源: https://reporter.nih.gov/project-details/3522019
• 关键词: biomedical automation; biomedical equipment purchase; biomedical equipment resource; computer network; computer program /software; computer system hardware; nuclear magnetic resonance spectroscopy; personal computers

The Department of Chemistry at the University of Wisconsin, Madison requests matching funds to purchase a Nuclear Magnetic Resonance (NMR) spectrometer to replace a ten year old 200 MHz NMR spectrometer used for routine high resolution NMR spectroscopy. The new spectrometer will operate at a field of 7.06 Tesla (300 MHz proton resonance); it will have both routine proton and carbon capabilities. An automatic sample changer will be added to the instrument to increase throughput of samples. To make the most effective use of the spectrometer the department also plans to upgrade the seven NMR data stations which are now used to carry out all of the off-line data processing. This new spectrometer is urgently needed in order to continue a number of research programs supported by the NIH. Although this equipment is located in the chemistry building, this facility serves the entire campus at the University of Wisconsin-Madison.

威斯康星大学麦迪逊分校化学系 请求配套资金购买核磁共振 (NMR) 光谱仪取代使用十年的 200 MHz NMR 光谱仪 常规高分辨率核磁共振波谱。新的光谱仪将 在 7.06 特斯拉场（300 MHz 质子共振）下运行；它将有 常规质子和碳能力。自动进样器 将被添加到仪器中以增加样品的通量。使 该部门还计划最有效地利用光谱仪 升级七个核磁共振数据站，这些数据站现在用于执行所有 离线数据处理。迫切需要这种新型光谱仪 为了继续 NIH 支持的一些研究项目。 虽然这个设备位于化学楼，但是这个 设施服务于威斯康星大学麦迪逊分校的整个校园。

项目成果

Copper(I)/ABNO-catalyzed aerobic alcohol oxidation: alleviating steric and electronic constraints of Cu/TEMPO catalyst systems.

• DOI: 10.1021/ja409241h
• 发表时间: 2013-10-23
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: Steves JE;Stahl SS
• 通讯作者: Stahl SS

Method for Small-Scale Production of Deuterochloroform.

小规模生产氘代氯仿的方法。

• DOI: 10.1021/acs.joc.8b01018
• 发表时间: 2018
• 期刊: The Journal of organic chemistry
• 作者: Tansukawat,NathaD;See,AlyaaE;Jiranuntarat,Sadudee;Corbin,JoshuaR;Schomaker,JenniferM
• 通讯作者: Schomaker,JenniferM

Synthesis and characterization of the 7-(4-aminomethyl-1H-1,2,3-triazol-1-yl) analogue of kabiramide C.

• DOI: 10.1021/np049670z
• 发表时间: 2005-02
• 期刊: Journal of natural products
• 影响因子: 5.1
• 作者: Chutima Petchprayoon;K. Suwanborirux;Reagan L. Miller;T. Sakata;G. Marriott

Copper-catalyzed recycling of halogen activating groups via 1,3-halogen migration.

• DOI: 10.1021/ja306446m
• 发表时间: 2012-10-03
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: Grigg RD;Van Hoveln R;Schomaker JM
• 通讯作者: Schomaker JM

Trimethylsilyl-Substituted Hydroxycyclopentadienyl Ruthenium Hydrides as Benchmarks to Probe Ligand and Metal Effects on the Reactivity of Shvo Type Complexes.

• DOI: 10.1021/om2007453
• 发表时间: 2012
• 期刊: Organometallics
• 影响因子: 2.8
• 作者: Casey CP;Guan H
• 通讯作者: Guan H