G8-2012 Ink-jet printed single-crystal organic photovoltaics (IPSOP)

G8-2012 喷墨印刷单晶有机光伏电池（IPSOP）

• 批准号: EP/K025651/1
• 负责人: Henning Sirringhaus
• 金额: $ 52.85万
• 依托单位: University of Cambridge
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2013
• 资助国家: 英国
• 起止时间: 2013 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FK025651%2F1
• 关键词: G8; 2012; Ink; jet; printed

87% of global energy production in 2010 was derived from unsustainable fossil fuels and as energy consumption grows, we urgently need to move towards renewable, clean energy sources to ensure national and international energy security. Only ~36 kWh/day/person could realistically be generated by non-solar renewables, falling short of the global target for energy requirements of 80 kWh/day/person. Therefore, without relying on nuclear energy, we must ensure that solar energy fills the gap. To meet demand, we require as many on- and off-grid photovoltaic (PV) technologies as possible and development of sustainable, low-energy and material-light technologies should be prioritized. In this context, ink-jet printing organic semiconductors is highly attractive.Our project aims to use similar processing techniques to demonstrate a dramatic step change in PV efficiency tomatch that of transistors. Such a step change requires a global consortium such as ours, including world-leading chemists (USA), physicists/engineers (UK) and material scientists (Japan) as well as knowledge of market requirements (Organic PV company). We aim to tackle the whole PV cycle, from materials to exploitation. In particular concentrating on (i) sustainable approaches to organic semiconductor synthesis, potentially allowing organic PVs to be made out of bio waste such as corn stover,(ii) creating highly ordered PVs using novel adapted ink-jet printing and vapor-phase deposition (and comparing the two techniques)(iii) quantitatively characterising the single crystal structure, physics and morphology(iv) characterizing the finished PVs, including stability and lifetime.Constant feedback between the groups will be used to optimize the materials and processing techniques to develop revolutionary >10% efficient sustainable PVs.

2010年，全球能源生产的87％来自不可持续的化石燃料，随着能源消耗的增长，我们迫切需要朝着可再生，清洁能源迈进，以确保国家和国际能源安全。实际上，只有〜36 kWh/天/人可以由非极性可再生能源产生，而不足以达到80 kWh/day/人的全球能源需求目标。因此，在不依赖核能的情况下，我们必须确保太阳能填补了空白。为了满足需求，我们需要尽可能多的网格光伏（PV）技术，并且应优先考虑可持续性，低能量和材料轻型技术的发展。在这种情况下，墨水打印有机半导体非常有吸引力。我们的项目旨在使用类似的处理技术来证明晶体管的PV效率变化急剧变化。这样的步骤改变需要一个全球财团，例如我们的联盟，包括世界领先的化学家（美国），物理学家/工程师（英国）和物质科学家（日本）以及市场需求知识（有机PV Company）。我们旨在解决从材料到剥削的整个光伏周期。特别是专注于（i）（i）有机半导体合成的可持续方法，有可能允许有机PV由诸如玉米秸秆等生物废物制成的有机PV，（ii）使用新颖的适应性墨水喷气打印和蒸气相结合（并比较两种技术）（iii II）（iii II）（iii II）（iii II），创建高度有序的PVS（III） PVS，包括稳定性和生命周期。组之间的反馈将用于优化材料和加工技术，以开发革命性> 10％效率的可持续性PV。

项目成果

The entangled triplet pair state in acene and heteroacene materials

并苯和杂并苯材料中的纠缠三重态对态

• DOI: 10.17863/cam.11233
• 发表时间: 2017
• 作者: Yong C

All-Inkjet-Printed, All-Air-Processed Solar Cells

• DOI: 10.1002/aenm.201400432
• 发表时间: 2014-10-07
• 期刊: ADVANCED ENERGY MATERIALS
• 影响因子: 27.8
• 作者: Jung, Sungjune;Sou, Antony;Sirringhaus, Henning
• 通讯作者: Sirringhaus, Henning

The entangled triplet pair state in acene and heteroacene materials.

• DOI: 10.1038/ncomms15953
• 发表时间: 2017-07-12
• 期刊: Nature communications
• 影响因子: 16.6
• 作者: Yong CK;Musser AJ;Bayliss SL;Lukman S;Tamura H;Bubnova O;Hallani RK;Meneau A;Resel R;Maruyama M;Hotta S;Herz LM;Beljonne D;Anthony JE;Clark J;Sirringhaus H
• 通讯作者: Sirringhaus H

Stability investigations of inverted organic solar cells with a sol-gel processed ZnSrO or ZnBaO electron extraction layer

具有溶胶-凝胶处理的 ZnSrO 或 ZnBaO 电子提取层的倒置有机太阳能电池的稳定性研究

• DOI: 10.1117/12.2023247
• 发表时间: 2013
• 作者: Pachoumi O

Identification of a triplet pair intermediate in singlet exciton fission in solution

• DOI: 10.1073/pnas.1503471112
• 发表时间: 2015-06-23
• 期刊: PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
• 影响因子: 11.1
• 作者: Stern, Hannah L.;Musser, Andrew J.;Walker, Brian J.
• 通讯作者: Walker, Brian J.