Interfacial domain structure of polycrystalline semiconducting polymer films

多晶半导体聚合物薄膜的界面域结构

• 批准号: EP/G068356/1
• 负责人: Henning Sirringhaus
• 金额: $ 16.73万
• 依托单位: University of Cambridge
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2009
• 资助国家: 英国
• 起止时间: 2009 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FG068356%2F1
• 关键词: Interfacial; domain; structure; polycrystalline; semiconducting

The objective of the proposed research is to use cutting-edge synchrotron-based techniques to answer fundamental questions regarding the operation of real-world organic electronic devices. Electronic devices based on organic (carbon-based) semiconductors are just beginning to enter the market place enabling a new generation of low-cost, flexible electronic displays and devices. Unlike traditional inorganic semiconductor materials such as Silicon, organic semiconductors have a highly complicated and often disordered film structure. Therefore to improve our understanding of the operation of these devices we need to fully characterise the structure of these films. Synchrotron-based microscopes are powerful tools that are ideally suited to this task that allow for the bulk and surface structure of materials to be probed with sub-micrometre resolution. Additionally, the use of lower energy soft X-rays with energies that match the molecular resonances in carbon-based materials allows for additional structural and chemical information to be extracted. The results of this research will help to enable next generation organic semiconductor materials and devices.

拟议的研究的目的是使用基于尖端同步加速器的技术来回答有关现实世界有机电子设备运行的基本问题。基于有机（碳基）半导体的电子设备刚刚开始进入市场，使新一代的低成本，灵活的电子显示器和设备。与传统的无机半导体材料（如硅）不同，有机半导体具有高度复杂且经常混乱的膜结构。因此，为了提高我们对这些设备运行的理解，我们需要充分表征这些膜的结构。基于同步加速器的显微镜是功能强大的工具，非常适合该任务，可以通过亚微米分辨率探测材料的整体和表面结构。此外，使用较低的能量软X射线与能量与碳基材料中的分子共振相匹配的能量可以提取其他结构和化学信息。这项研究的结果将有助于实现下一代有机半导体材料和设备。

项目成果

Molecular Miscibility of Polymer-Fullerene Blends

• DOI: 10.1021/jz101276h
• 发表时间: 2010-11-04
• 期刊: JOURNAL OF PHYSICAL CHEMISTRY LETTERS
• 影响因子: 5.7
• 作者: Collins, Brian A.;Gann, Eliot;Ade, Harald
• 通讯作者: Ade, Harald

Polymer Blend Solar Cells Based on a High-Mobility Naphthalenediimide-Based Polymer Acceptor: Device Physics, Photophysics and Morphology

• DOI: 10.1002/aenm.201000035
• 发表时间: 2011-03-18
• 期刊: ADVANCED ENERGY MATERIALS
• 影响因子: 27.8
• 作者: Moore, Jennifer R.;Albert-Seifried, Sebastian;Sirringhaus, Henning
• 通讯作者: Sirringhaus, Henning

Voltage-dependent photocurrent transients of PTB7:PC70BM solar cells: Experiment and numerical simulation

• DOI: 10.1063/1.4813612
• 发表时间: 2013-07-21
• 期刊: JOURNAL OF APPLIED PHYSICS
• 影响因子: 3.2
• 作者: Li, Zhe;Lakhwani, Girish;McNeill, Christopher R.
• 通讯作者: McNeill, Christopher R.