Construction of External-stimuli Responsive Coordination Space

外部刺激响应协调空间的构建

• 批准号: 16074203
• 负责人: OSHIO Hiroki
• 金额: $ 27.71万
• 依托单位: University of Tsukuba
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research on Priority Areas
• 财政年份: 2004
• 资助国家: 日本
• 起止时间: 2004 至 2007
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-16074203/
• 关键词: Multinuclear metal complexes; Coordination space; External stimuli; 金属錯体; 多核錯体; 磁性; スピン平衡; 多段階スピン平衡錯体; 多重安定性分子; 酸化物クラスター

This project aims at developments of external-stimuli responsive coordination space and explores the new functions. We repot here two types of systems, 1) Cyanide-bridged cubic clusters: Application to, 2) Cyanide-bridged cubic clusters with multi-step redox or ferromagnetic behavior.Cyanide ions are useful tools in the construction of coordination complexes from discrete units to 3-D architectures, and cyanide bridged compounds have garnered intense research interest because of their solid state properties. Prussian blue and some analogues exhibit magnetic ordering with Curie temperatures ranging from 5 K to room temperature, while some discrete molecules show superparamagnetism2 and spin states conversion with external stimulus. We report here (1) Possible application as a cathode in rechargeable lithium ion batteries in an iron cube ([FeII4FeIII4(μ-CN)12(tp)8] (1), and (2) Thermal induced electron transfer in an iron-cobalt square ([Co2Fe2 (CN) 6 (tp) 2 (bpy) 4] (PF6) 2 (2)).

该项目旨在发展外部刺激响应式协调空间，并探索新功能。 We repot here two types of systems, 1) Cyanide-bridged cubic clusters: Application to, 2) Cyanide-bridged cubic clusters with multi-step redox or ferromagnetic behavior.Cyanide ions are useful tools in the construction of coordination complexes from discrete units to 3-D architectures, and cyanide bridged compounds have garnered intense research Interest because of their solid state properties.普鲁士蓝色和一些类似物以库里温度从5 k到室温，而某些离散分子显示了超paramagnetism2和自旋状态与外部刺激的转化。我们在这里报告（1）可能在铁立方（[FEII4FEIII4（μ-CN）12（TP）8]（1）和（2）在铁ob骨架中的热诱导电子转移（[CO2FE2（CN）6（CN）6（CN）6（cn）6（bpy）2（bpy）2（2（pf），

项目成果

Magnetic Bistability and Single-Crystal-to-Single-Crystal Transfomation Induced by Guest Desorption

客体解吸引起的磁双稳定性和单晶到单晶的转变

• 发表时间: 2007
• 期刊: J. Am. Chem. Soc. 129
• 作者: M. Nihei;L. Han;H. Oshio
• 通讯作者: H. Oshio

Synthesis, structure and magnetic property of an iron(II) comples with nitronyl nitroxide

硝基硝基氧铁(II)络合物的合成、结构及磁性

• 发表时间: 2007
• 期刊: Polyhedron 26
• 作者: M. Nihei;T. Maeshima;Y. Kose;H. Oshio
• 通讯作者: H. Oshio

Syntheses, Structures and Magnetic Properties of Mixed-valence Pentanuclear [M_n^<II>M_n^<III>] and Hexanuclear [C_o^<II>C_o^<III>_2] Complexes Derived from 3-formylsalicylic acid

3-甲酰水杨酸混合价五核[M_n^<II>M_n^<III>]和六核[C_o^<II>C_o^<III>_2]配合物的合成、结构和磁性

• 发表时间: 2007
• 期刊: Polyhedron 26
• 作者: T. Shiga;H. Oshio
• 通讯作者: H. Oshio

"Iron(III) Spin Crossover Coumpounds" Topics in Current Chemistry Vol.233, Spin Crossover in Transition Metal Compounds I

“铁(III)自旋交叉化合物”当前化学专题第233卷，过渡金属化合物中的自旋交叉I

• 发表时间: 2004
• 作者: Y.Yamamoto;S.Takada;N.Miyaura;大塩 寛紀
• 通讯作者: 大塩 寛紀

Single Molecule Magnets and their Quantum Tunneling Dynamics of Spin Reorientaion

单分子磁体及其自旋重定向的量子隧道动力学

• 发表时间: 2008
• 作者: H.;Oshio
• 通讯作者: Oshio