Innovative Synthetic Reactions

创新的合成反应

• 批准号: 09238104
• 负责人: MURAI Shinji
• 金额: $ 14.34万
• 依托单位: Osaka University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research on Priority Areas
• 财政年份: 1997
• 资助国家: 日本
• 起止时间: 1997 至 1999
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-09238104/
• 关键词: organic synthesis; new chemistry; new reaction; covalent bond; transition metal; reaction media; theory; catalyst; 新化学現像; 触媒設計; 発見; 金属有機化学; 有機化学; 結合

The objective of this research project is to discover new phenomena leading to new reactions which will serve as basis for the development of synthetic chemistry in the new century. The efforts have been expected to be devoted to find new efficient method for the cleavage of unreactive bonds between carbon and other elements including carbon, nitrogen, oxygen, and hydrogen.For this purpose various approaches, mainly on the basis of organometallic reactions, have been undertaken. Rational design-based approach as well as exploratory approach was applied. The reactions in which simultaneous reactants-reagents interaction at many reaction centers have been extensively looked for. As the results, various innovative synthetic reactions have been developed successfully. The examples are the catalytic addition of otherwise unreactive C-H bonds to multiple bonds and catalytic, highly stereoselective polymerization.Cooperation among eighty research groups has been successfully done through several symposiums during the three years research period.

该研究项目的目的是发现新的现象，导致新的反应，这将是新世纪合成化学的发展的基础。已经预计，预计这项努力是为了找到新的有效方法来裂解碳和其他元素之间的不反应性键，包括碳，氮，氧气和氢。为此，已经采用了各种方法，主要是基于器官量反应的各种方法。采用了基于理性设计的方法以及探索方法。广泛寻找许多反应中心的反应物 - 反应相互作用的反应。结果，已经成功开发出了各种创新的合成反应。示例是在多个键和催化高度立体选择性聚合的催化添加其他不反应的C-H键。在三年研究期内，通过几个研讨会成功完成了八十个研究小组的合作。

项目成果

M.Sawamura, Y.Kuninobu, E.Nakamura: "Half-Sandwich Metallocene Embedded in a Spherically Extended p-Conjugate System. Synthesis, Structure, and Electrochemistry of Rh (η5-C60Me5)(CO)2"J.Am.Chem.Soc.. 122. 12407-12408 (2000)

M.Sawamura、Y.Kuninobu、E.Nakamura：“嵌入球形扩展 p 共轭体系中的半夹心茂金属。Rh (η5-C60Me5)(CO)2 的合成、结构和电化学”J.Am.Chem .社会.. 122. 12407-12408 (2000)

S.Kawata(分担執筆): "Photorefractive Optics"Academic Press. 570 (2000)

S.Kawata（撰稿人）：《光折变光学》学术出版社 570 (2000)。

H.Isobe, H.Tokuyama, M.Sawamura, E.Nakamura: "Synthetic and Computational Studies on Symmetry-Defined Double Cycloaddition of a New Tris-Annulating Reagent to C_<60>" J.Org.Chem.62. 5034-5041 (1997)

H.Isobe、H.Tokuyama、M.Sawamura、E.Nakamura：“新型 Tris 成环试剂与 C_<60> 的对称定义双环加成的合成和计算研究”J.Org.Chem.62。

T.Sato,F.Kakiuchi,N.Chatani,S.Murai: "Ruthenium-Catalyzed Reactions of Acyclic a,b-Enones with Olefins and Their Reaction Mechanisms." Chem.Lett.893-894 (1998)

T.Sato、F.Kakiuchi、N.Chatani、S.Murai：“钌催化的无环 a,b-烯酮与烯烃的反应及其反应机制。”

S.Shoji and S.Kawata: "Photofabrication of three-dimensional photonic crystals by multibeam laser interference into a photopolymerizable resin"Appl.Phys.Lett.. 76・16. 2668-2670 (2000)

S.Shoji 和 S.Kawata：“通过多束激光干涉光聚合树脂来制造三维光子晶体”Appl.Phys.Lett. 76・16 (2000)。