Development of New Complex Catalyst System for the Utilization of Carbon Monoxide

用于一氧化碳利用的新型复合催化剂体系的开发

• 批准号: 60470088
• 负责人: MURAI Shinji
• 金额: $ 3.52万
• 依托单位: Osaka University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (B)
• 财政年份: 1985
• 资助国家: 日本
• 起止时间: 1985 至 1986
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-60470088/
• 关键词: Metal-metal bond; 異元素間結合; カルボニル化触媒

The purpose of this project has been to develop the new and efficient catalytic system for the utilization of carbon monoxide that is the one of the most important raw material of the comming industry.The basic design of the developing new catalyst is based on the possible unique reactivity of metal complexes having a common element and transition metal bond. Such metal-metal bonded complexes has been expected to exibit the enhanced reactivity of the common element toward specific sites in the organic substrates, these forcing the bond formation between the specific sites in the molecule with the transition metal moiety. This new concept has been revealed to be very much successful and various type of novel catalytic reactions that enables incorporation of carbon monoxide has been found.

该项目的目的是开发用于利用一氧化碳的新的，有效的催化系统，这是碳二氧化碳的最重要原材料之一。开发的新催化剂的基本设计基于具有共同元素和过渡金属键的金属配合物的可能独特反应性。预计这种金属金属键合复合物可以超出有机底物中特定位点的共同元件的增强反应性，这些反应性迫使分子中特定位点之间的键形成与过渡金属部分。这一新概念已经揭示出非常成功，并且已经发现了能够掺入一氧化碳的各种新型催化反应。

项目成果

神戸宣明: Chem.Lett.269-272 (1987)

神户信明：Chem.Lett.269-272 (1987)

Murai, Shinji: ""Cobalt Carbonyl Catalyzed Reactions of Lactones with Hydrosilane and Carbon Monoxide. A Novel Synthetic Method for the Introduction of the Siloxymethylidene Group"" J. Am. Chem. Soc.108. 7361-7373 (1986)

Murai, Shinji：“羰基钴催化内酯与氢硅烷和一氧化碳的反应。

村井真二: J.Am.Chem.Soc.108. 7361-7373 (1986)

村井真司：J.Am.Chem.Soc.108 7361-7373 (1986)

村井真二: J.Molecular Catalysis.

村井信司：《分子催化杂志》。

Murai, Shinji: ""Desilylative Chlorostannation of Silylmethyl-Substituted Cyclopropanes by <SnCl_4> to Give 3-Butenyltrichlorostannanes. An Entry to Homoallylmetal Compounds"" Organometallics. 6. 212-213 (1987)

Murai, Shinji：“通过 <SnCl_4> 对甲硅烷基甲基取代的环丙烷进行脱甲硅烷基氯锡化，得到 3-丁烯基三氯锡烷。