I-Corps: Solution-Processed, High-Quality Indium Tin Oxide (ITO) Films for Perovskite-Based Tandem Solar Cells

I-Corps：用于钙钛矿串联太阳能电池的溶液加工高品质氧化铟锡 (ITO) 薄膜

• 批准号: 2041928
• 负责人: Dawen Li
• 金额: $ 5万
• 依托单位: University of Alabama Tuscaloosa
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-08-01 至 2023-01-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2041928&HistoricalAwards=false
• 关键词: Corps; Solution; Processed; Quality; Indium

The broader impact/commercial potential of this I-Corps project is the development of new solar cells. Lightweight and flexible solar panels are attractive because of high power output, and easy transportation and installation for a given space. Currently, such solar panels on the market offer efficiencies of only 15%. The goal of the proposed technology is to provide a light-weight solar panel with high power output and long lifespan that also may reduce operational cost in electricity or generate excess electricity. This project will explore applications for residential, agricultural, and other users. This I-Corps project is based on the development of a solution-processed, high-quality transparent electrode for perovskite-based tandem solar cells. In perovskite-based tandem solar cells, transparent indium tin oxide (ITO) thin films are employed to serve as the top contact and/or interconnecting layer between top and bottom sub-cells. To realize low-cost fabrication of perovskite solar panels through roll-to-roll printing in an ambient environment, room-temperature solution-processed ITO is desirable. However, with commonly used hotplate annealing, ITO thin films are subjected to high temperatures for long durations, up to several hours at a time, to attain high-quality film. Since a hotplate heats all stacking layers simultaneously, the flexible substrates and perovskite absorber layer may be damaged because of the limited temperature resistance. The proposed technology uses photonic irradiation to achieve rapid and layer-specific annealing for transparent ITO film without damaging the underlying stacking layers. Unlike hotplate heating in which each layer shares the same temperature via thermal conduction, photonic treatment may selectively supply energy to a specific layer through photon absorption. The capability to achieve high-quality solution-processed ITO enabled by rapid and layer-specific photonic annealing paves the way for large-volume manufacturing of perovskite-based tandem solar cells by high-speed roll-to-roll printing.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该 I-Corps 项目更广泛的影响/商业潜力是新型太阳能电池的开发。轻质且灵活的太阳能电池板因其高功率输出以及在给定空间内易于运输和安装而具有吸引力。目前，市场上此类太阳能电池板的效率仅为 15%。所提出技术的目标是提供一种具有高功率输出和长寿命的轻质太阳能电池板，还可以降低电力运营成本或产生多余的电力。该项目将探索住宅、农业和其他用户的应用。该 I-Corps 项目基于为钙钛矿串联太阳能电池开发溶液处理的高质量透明电极。在基于钙钛矿的串联太阳能电池中，透明氧化铟锡（ITO）薄膜被用作顶部和底部子电池之间的顶部接触和/或互连层。为了在环境环境中通过卷对卷印刷实现钙钛矿太阳能电池板的低成本制造，需要室温溶液处理的 ITO。然而，在常用的热板退火中，ITO 薄膜需要长时间处于高温下，一次长达几个小时，以获得高质量的薄膜。由于加热板同时加热所有堆叠层，因此柔性基板和钙钛矿吸收层可能由于有限的耐温性而损坏。所提出的技术使用光子照射来实现透明 ITO 薄膜的快速和层特定退火，而不损坏下面的堆叠层。与每层通过热传导共享相同温度的热板加热不同，光子处理可以通过光子吸收选择性地向特定层提供能量。通过快速和层特定的光子退火实现高质量溶液处理的 ITO 的能力，为通过高速卷对卷印刷大规模制造基于钙钛矿的串联太阳能电池铺平了道路。该奖项反映了 NSF 的法定使命，并通过使用基金会的智力优点和更广泛的影响审查标准进行评估，被认为值得支持。