Nonlinear Dynamics of Entangled Polymers with Well-controlled Long-chain Branching

具有良好控制的长链支化的缠结聚合物的非线性动力学

• 批准号: 1105135
• 负责人: Shi-Qing Wang
• 金额: $ 35.98万
• 依托单位: University of Akron
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2011
• 资助国家: 美国
• 起止时间: 2011-08-15 至 2016-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1105135&HistoricalAwards=false
• 关键词: Nonlinear; Dynamics; Entangled; Polymers; Well; Nonlinear; Dynamics; Entangled; Polymers; Well

TECHNICAL SUMMARYThis research aims to probe how molecular design of chain architecture can be employed to affect nonlinear dynamics of entangled polymers. The proposed research will attempt to control the structure of long-chain branching (LCB) in various polyisoprene and polybutadiene-based melts, and determine the differences between melts with LCB and corresponding linear melts under different conditions of large deformation. The specific objectives of the proposed work are as follows: 1) Determine interfacial yielding characteristics of the various LCB polymers to contrast with corresponding linear counterparts; 2) Explore how melt strength depends on the specific chain architecture, e.g., the number of branching points per chain; 3) Examine whether the entanglement network with LCB may suffer strain localization upon large deformation; 4) Identify key molecular structural parameters that define/determine the cohesion and dictates nonlinear responses to large deformations; 5) Study the effect of mixing different components of LCBs or LCB and linear chains on the nonlinear dynamics. To achieve these goals, both simple and uniaxial extension will be carried out involving either startup or step strain. In all cases, effective particle-tracking velocimetric (PTV) observations will be indispensable and systematically carried out. In the case of shear, a circular Couette shear cell will be employed with PTV capability. Uniaxial extension will be realized either with the counter-rotating double-cylinder device or Instron where in situ PTV measurements will also be performed. NON-TECHNICAL SUMMARYThis research aims to explore and identify guiding fundamental principles that may find application in more efficient and energy-saving manufacturing of polymeric materials. These principles will ultimately emerge from the present proposed work, aimed to determine how different molecular designs of polymeric materials would affect the processing ability of plastics and rubbers. The outcome of the proposed work should lead to explicit information valuable to the plastic and rubber industries. At the same time, the experimental activities are expected to stimulate theoretical development in the field of polymer physics. More broadly, the PI plans to consolidate the findings from this research into a textbook, which would include all the key results emerging from his contributions to this field. Since the nature of the proposed research is visualization-intensive, complex physical phenomena can receive intuitive interpretations, thus providing attractive educational materials for students in middle and high schools to perceive how science is done. As part of the research activities, an international collaboration has also been initiated with the Changchun Institute of Applied Chemistry of the Chinese Academy of Sciences, aiming to carry out computer simulations complementary to the various proposed experiments.

技术摘要这项研究旨在探讨如何使用链结构的分子设计来影响纠缠聚合物的非线性动力学。 拟议的研究将尝试控制各种聚甲苯和多丁二烯基熔体中长链分支（LCB）的结构，并确定在大变形的不同条件下使用LCB的熔体和相应的线性熔体之间的差异。 所提出的工作的特定目标如下：1）确定各种LCB聚合物的界面屈服特性，以与相应的线性对应物形成鲜明对比； 2）探索熔体强度如何取决于特定的链结构，例如每个链的分支点数； 3）检查具有LCB的纠缠网络是否会在大变形后遭受应变定位； 4）确定定义/确定凝聚力的关键分子结构参数，并决定对大变形的非线性响应； 5）研究混合LCB或LCB和线性链不同组件对非线性动力学的影响。 为了实现这些目标，将进行简单和单轴扩展，涉及启动或步骤应变。 在所有情况下，有效的粒子跟踪速度计（PTV）观察结果都是必不可少的，并且有系统地进行。 在剪切的情况下，将采用具有PTV能力的圆形COUETTE剪切电池。 单轴扩展将使用反向旋转的双缸设备或Instron实现，在该设备上也将进行原位PTV测量。 非技术摘要这项研究旨在探索和确定指导性的基本原理，这些原理可能会在更高效，更节能的聚合物材料制造中应用。 这些原则最终将从目前的拟议工作中得出，旨在确定聚合物材料的不同分子设计如何影响塑料和橡胶的加工能力。 拟议工作的结果应导致对塑料和橡胶行业有价值的明确信息。 同时，预期实验活动将刺激聚合物物理领域的理论发展。 更广泛地说，PI计划将这项研究的发现巩固到一本教科书中，其中包括从他对该领域的贡献中出现的所有关键结果。 由于拟议的研究的性质是可视化密集型，因此复杂的物理现象可以接受直观的解释，从而为中学和中学的学生提供有吸引力的教育材料，以感知科学的完成方式。 作为研究活动的一部分，国际合作还与中国科学院应用化学研究所进行了国际合作，旨在进行计算机模拟，以补充各种拟议的实验。