SGER: Metathesis-Doped Polyacetylene

SGER：复分解掺杂聚乙炔

• 批准号: 0320583
• 负责人: Michael Sponsler
• 金额: $ 10万
• 依托单位: Syracuse University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-07-01 至 2005-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0320583&HistoricalAwards=false
• 关键词: SGER; Metathesis; Doped; Polyacetylene

Michael Sponsler, Department of Chemistry, Syracuse University, is supported by the Inorganic, Bioinorganic and Organometallic Chemistry Program for studies of "metathesis-doped polyacetylene". He is incorporating metathesis-active ruthenium compounds into films of polyacetylene to determine the electronic properties of conjugated organometallic structures. By capping polyacetylene oligomers with ruthenium compounds, long-chain ruthenapolyenes and diruthenapolyenes can be prepared in viscous solution and thin films, where they should be stable. The conductivity of these films will be measured and correlated with various structural parameters. In a related component of this research, modified ruthenium complexes will be used to make connections between nanoscale and macroscale electronic components. This Small Grant for Exploratory Research (SGER) supports high risk/high impact research in molecular electronics and nanotechnology. This interdisciplinary project will also provide graduate and undergraduate students with training in these important areas.

锡拉丘兹大学化学系的迈克尔·斯普斯勒（Michael Sponsler）得到了“掺杂多乙烯”的无机，生物有机和有机金属化学计划的支持。他将元矫正活性唯一化合物掺入聚乙炔膜中，以确定共轭有机金属结构的电子特性。通过用氟化合物限制聚乙炔寡聚物，可以在粘性溶液和薄膜中制备长链氟乙烯和唯一的二苯二酚，在那里应保持稳定。这些膜的电导率将与各种结构参数进行测量并相关。在这项研究的相关组成部分中，将使用改良的钌配合物来建立纳米级和宏观电子组件之间的连接。这项用于探索性研究（SGER）的小赠款支持分子电子和纳米技术的高风险/高影响研究。这个跨学科项目还将在这些重要领域为研究生和本科生提供培训。