U.S.-Japan Cooperative Research: Generation and Detection of Transient Metal Containing Molecules

美日合作研究：瞬态含金属分子的生成和检测

• 批准号: 9314913
• 负责人: Timothy Steimle
• 金额: $ 2.17万
• 依托单位: Arizona State University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1994
• 资助国家: 美国
• 起止时间: 1994-04-01 至 1997-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9314913&HistoricalAwards=false
• 关键词: U.S.; Japan; Cooperative; Research; Generation

9314913 Steimle This award supports a two-year cooperative research project between Professor Timothy Steimle, Department of Chemistry and Biochemistry, Arizona State University, and Professor Shuji Saito, Institute for Molecular Science, Okazaki National Research Institutes, Okazaki, Japan. In addition, two graduate students from Arizona State University and several scientists from Tokyo University and Shizuoka University will participate in the project. This collaborative effort is motivated by both practical and fundamental scientific interests. Transient metal containing compounds are important elements in processes such as rf- induced chemical etching and chemical vapor deposition. The proposed millimeter wave and optical spectroscopic detection schemes will be sensitive, non-invasive means of monitoring and controlling the chemistry of such systems. In addition, there are many fundamental scientific problems associated with metal containing radicals, not the least of which is their electronic and structural characterization (i.e. bond lengths and angles, electronic state distribution, m.o. description, etc.) The U.S. and Japanese teams have complementary theoretical and experimental expertise. The scientists at Okazaki have diode laser spectroscopic capabilities; the Tokyo University scientists have Fourier transform microwave capabilities, and the Shizuoka University group has millimeter wave capabilities. Cw-dye laser optical spectroscopy and pump/probe microwave optical double resonances of molecular beam samples will be performed at Arizona State University. ***

9314913 Steimle该奖项支持亚利桑那州立大学化学和生物化学系教授Timothy Steimle教授与日本Okazaki国家研究机构Okazaki National Research Institutes的Shuji Saito教授之间的为期两年的合作研究项目。 此外，来自亚利桑那州立大学的两名研究生以及东京大学和Shizuoka大学的几位科学家将参加该项目。 这项合作的努力是由实践和基本科学利益促进的。 瞬时金属含有化合物是RF诱导的化学蚀刻和化学蒸气沉积等过程中的重要元素。 提出的毫米波和光谱检测方案将是敏感的，无创的方法，用于监测和控制此类系统的化学。 此外，与含有自由基的金属相关的基本科学问题，其中最重要的是它们的电子和结构表征（即键长和角度和角度，电子状态分布，M.O.描述等），美国和日本团队具有互补的理论和实验专业知识。 Okazaki的科学家具有二极管激光光谱功能；东京大学的科学家具有傅立叶变换微波功能，而Shizuoka University Group具有毫米波能力。 CW-DYE激光光谱和分子束样品的泵/探针微波光学双共振将在亚利桑那州立大学进行。 ***