The Electrochemical Polymerization of Bis-2-Pyrrolyl Conjugated Monomers to Form Highly Conducting Polymers

双-2-吡咯基共轭单体的电化学聚合形成高导电聚合物

• 批准号: 9307732
• 负责人: John Reynolds
• 金额: $ 27万
• 依托单位: University of Florida
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1993
• 资助国家: 美国
• 起止时间: 1993-08-01 至 1996-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9307732&HistoricalAwards=false
• 关键词: Electrochemical; Polymerization; Bis; Pyrrolyl; Conjugated

9307732 Reynolds This award is made in the Advanced Materials and Processing Program in support of the collaborative research of Professors Reynolds and Katritzky at the University of Florida. Support is provided by the Divisions of Chemistry and Materials Research. Novel bis-2-pyrrolyl conjugated monomers containing substituted benzenes, carbazoles and fluorenes as internal units will be synthesized and electrochemically polymerized to highly conducting polymers. The main goal of the research is to develop a fundamental understanding of the electropolymerization and film-deposition processes that occur during oxidative polymerization and to direct the electrosynthesis to form polymers with enhanced properties. %%% Polypyrroles with higher degrees of long range order will be synthesized which will have higher electrical conductivities and improved environmental stabilities relative to presently available polymers. These aspects are important in electrostatic charge dissipation and electric field grading applications. ***

9307732 Reynolds该奖项是在佛罗里达大学的Reynolds和Katritzky教授的合作研究中在高级材料和加工计划中颁发的。支持由化学和材料研究的划分提供。 新型的BIS-2-吡咯基偶联的单体，含有取代的苯，甲壳唑和氟作为内部单元，将合成并在电化学上聚合到高度导电聚合物。该研究的主要目的是对氧化聚合过程中发生的电聚合和膜沉积过程的基本了解，并将电气合成以增强性能形成聚合物。 将合成具有较高远距离顺序的高度级别的%% %%脊髓吡咯，相对于目前可用的聚合物，将具有较高的电导率和改善的环境稳定性。这些方面在静电电荷耗散和电场分级应用中很重要。 ***