Phosphorus-based ionic liquids and ligands for catalysis

磷基离子液体和催化配体

• 批准号: 354777-2007
• 负责人: Alper, Howard
• 金额: $ 5.46万
• 依托单位: University of Ottawa
• 依托单位国家: 加拿大
• 项目类别: Collaborative Research and Development Grants
• 财政年份: 2009
• 资助国家: 加拿大
• 起止时间: 2009-01-01 至 2010-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=431425
• 关键词: Phosphorus; based; ionic; liquids; ligands

Transition metal catalyzed reactions are of considerable value for a number of industrialized processes. This project is concerned with the application of phosphonium-based ionic liquids and phosphine liquids to metal catalized carbonylation, oxidation, cyclocarbonylation, as well as oxidative and reductive carbonylation reactions. The use of environmentally attractive ionic liquids, as well as conducting a number of atom economy reactions, provides a green science approach to catalysis of potential value to the commodity, petrochemical, polymer, and pharmaceutical industries. Discovering effective phosphine ligands for metal catalyzed reactions, can have significant commercial value.

过渡金属催化反应对于许多工业化过程具有相当大的价值。该项目涉及鏻基离子液体和膦液体在金属催化羰基化、氧化、环羰基化以及氧化和还原羰基化反应中的应用。使用对环境有吸引力的离子液体，以及进行许多原子经济反应，为商品、石化、聚合物和制药行业的潜在价值催化提供了一种绿色科学方法。发现用于金属催化反应的有效膦配体具有重大的商业价值。