LINK-FUNCTIONALIZED POLYMERS VIA ROMP FOR STUDYING MECHANOCHEMISTRY

通过 ROMP 连接功能化聚合物用于研究机械化学

• 批准号: 7358004
• 负责人: JEFFREY MOORE
• 金额: $ 0.28万
• 依托单位: UNIVERSITY OF CALIFORNIA-IRVINE
• 依托单位国家: 美国
• 财政年份: 2006
• 资助国家: 美国
• 起止时间: 2006-08-29 至 2007-07-31
• 项目状态: 已结题
• 来源: https://reporter.nih.gov/project-details/7358004
• 关键词: polymers

This subproject is one of many research subprojects utilizing the resources provided by a Center grant funded by NIH/NCRR. The subproject and investigator (PI) may have received primary funding from another NIH source, and thus could be represented in other CRISP entries. The institution listed is for the Center, which is not necessarily the institution for the investigator. Our project researches stress-induced reactions by incorporating a single mechanically responsive unit into the center of a polymer backbone to produce a link-functionalized polymer. The synthesis of these link-functionalized polymers via ROMP is currently being investigated. The initial link being examined is an anthracene unit. Fluorescence depolarization is being used to determine if the anthracene link is in the center of the polymer chain.

该子项目是利用NIH/NCRR资助的中心赠款提供的资源的许多研究子项目之一。子弹和调查员（PI）可能已经从其他NIH来源获得了主要资金，因此可以在其他清晰的条目中代表。列出的机构适用于该中心，这不一定是调查员的机构。我们的项目通过将单个机械响应的单元纳入聚合物主链的中心以产生链路官能化的聚合物来研究应力诱导的反应。目前正在研究这些连接官能化聚合物的合成。正在检查的最初链接是蒽单元。荧光去极化用于确定蒽环节是否位于聚合物链的中心。