Transition Metal Alkane Sigma Complexes by Solid-State Synthesis Routes: Defining and Exploiting a New Area of Organometallic Chemistry.

通过固态合成路线制备过渡金属烷烃西格玛配合物：定义和开发有机金属化学的新领域。

• 批准号: EP/K035681/1
• 负责人: Stuart Macgregor
• 金额: $ 24.41万
• 依托单位: Heriot-Watt University
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2013
• 资助国家: 英国
• 起止时间: 2013 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FK035681%2F1
• 关键词: Transition; Metal; Alkane; Sigma; Complexes

Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.

目前，GtR 中尚未提供所有资助研究的摘要。这通常是因为在提交提案时不需要摘要，但可能是因为它包含个人详细信息等敏感信息。

项目成果

Stability and C-H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism.

钯 (I) 和铂 (I) 金属自由基的稳定性和 C-H 键活化反应：碳到金属氢原子转移和有机金属自由基反弹机制。

• DOI: http://dx.10.1021/jacs.3c04167
• 发表时间: 2023
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: Krämer T

A Series of Crystallographically Characterized Linear and Branched s-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane.

一系列晶体学表征的直链和支链 s-烷烃铑配合物：从丙烷到 3-甲基戊烷。

• DOI: http://dx.10.1021/jacs.1c00738
• 发表时间: 2021
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: Bukvic AJ

Solid-state synthesis and characterization of s-alkane complexes, [Rh(L2)(?(2),?(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine).

s-烷烃配合物[Rh(L2)(?(2),?(2)-C7H12)][BAr(F)4]（L2=二齿螯合膦）的固态合成和表征。

• DOI: http://dx.10.1021/ja510437p
• 发表时间: 2015
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: Pike SD

21st Century Challenges in Chemical Crystallography II - Structural Correlations and Data Interpretation

21 世纪化学晶体学的挑战 II - 结构相关性和数据解释

• DOI: http://dx.10.1007/430_2020_77
• 发表时间: 2020
• 作者: Algarra A

Solid-State Confinement Effects in Selective exo -H/D Exchange in the Rhodium s-Norbornane Complex [(Cy 2 PCH 2 CH 2 PCy 2 )Rh(? 2 :? 2 -C 7 H 12 )][BAr F 4 ]

铑 s-降冰片烷配合物中选择性 exo -H/D 交换的固态限制效应 [(Cy 2 PCH 2 CH 2 PCy 2 )Rh(? 2 :? 2 -C 7 H 12 )][BAr F 4 ]

• DOI: http://dx.10.1002/hlca.202200154
• 发表时间: 2023
• 期刊: Helvetica Chimica Acta
• 影响因子: 1.8
• 作者: Krämer T