MOST-H2 - Novel metal-organic framework adsorbents for efficient storage of hydrogen - Project 101058547

MOST-H2 - 用于高效储存氢气的新型金属有机骨架吸附剂 - 项目 101058547

• 批准号: 10057499
• 金额: $ 45.79万
• 依托单位: UNIVERSITY OF CAMBRIDGE
• 依托单位国家: 英国
• 项目类别: EU-Funded
• 财政年份: 2022
• 资助国家: 英国
• 起止时间: 2022 至 无数据
• 项目状态: 未结题
• 来源: https://gtr.ukri.org/projects?ref=10057499
• 关键词: MOST; H2; Novel; metal; organic

Widespread use of hydrogen as an energy carrier is a key priority for the EU, in order to achieve its climate and energy transition targets. Developing sustainable, efficient and safe hydrogen storage technologies has, however, proved challenging. MOST-H2, in full alignment with the requirements of HORIZON-CL4-2021-RESILIENCE-01-17, proposes an integrated multiscale lab-to-tank approach to develop, validate and demonstrate innovative, low cost cryo-adsorptive hydrogen storage, using monolithic Metal-Organic Framework (MOF) adsorbents, with an optimal combination of volumetric and gravimetric capacity, but also a small environmental footprint. Advanced synthetic strategies and sophisticated computational techniques, including molecular simulation and machine learning, will be combined in a cyclic materials development approach, to deliver new high performance, sustainable-by-design MOF adsorbents. The main aim is to computationally design, then synthesise and validate experimentally, ultra porous MOFs with usable storage capacities above 10 wt% and 50 g/L on a materials basis, at an operating pressure below 100 bar. This represents an essential step towards more efficient, intrinsically safer and cost effective storage solutions, compared to conventional hydrogen storage technologies. An important part of the project will be devoted to developing and upscaling monolithic forms of optimal MOF materials to allow easy integration into a cryo-adsorption storage tank, specifically designed for this purpose, which will be tested in a TRL 5 environment. The outcomes, coupled with full life cycle analysis and techno-economic assessment of MOST-H2 technology, with a view to selected end uses (rail and road applications), will form the basis for elaborating future market penetration plans through a solid horizontal dissemination and exploitation strategy

为了实现其气候和能量过渡目标，将氢用作能量载体的广泛使用是欧盟的关键优先级。然而，开发可持续，高效和安全的氢存储技术已被证明是具有挑战性的。大多数H2与Horizo​​n-CL4-2021-弹性-01-17完全保持一致足迹。先进的合成策略和复杂的计算技术（包括分子模拟和机器学习）将结合在环状材料开发方法中，以提供新的高性能，可持续的逐效MOF吸附剂。主要目的是在计算设计上进行计算设计，然后在材料基础上以低于10 wt％和50 g/l的可用存储能力在100 bar的操作压力下合成和实验验证具有可用存储能力的超多孔MOF。与传统的氢存储技术相比，这是朝着更高效，更安全和成本效益的存储解决方案迈出的重要一步。该项目的一个重要部分将致力于开发和增强最佳MOF材料的整体形式，以便于轻松地集成到冷冻吸附储罐中，这是专门为此目的设计的，将在TRL 5环境中进行测试。结果，加上大多数H2技术的完整生命周期分析和技术经济评估，并考虑了选定的最终用途（铁路和道路应用），将是通过稳固的水平传播和剥削策略阐明未来市场渗透计划的基础