Development of a quantum-cascade laser-based instrument for high sensitivity measurement of nitrous acid

开发基于量子级联激光的高灵敏度亚硝酸测量仪器

• 批准号: 23651014
• 负责人: YABUSHITA Akihiro
• 金额: $ 2.66万
• 依托单位: Kyoto University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Challenging Exploratory Research
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011 至 2012
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23651014/
• 关键词: ガス状亜硝酸; エアロゾル; レーザー; 装置開発; 大気環境化学; 量子カスケードレーザー; キャビティーリングダウン分光; 環境計測機器開発; 大気化学

Laser-based instruments for measurement of gaseous nitrous acid were developed by using techniques of cavity ring-down spectroscopy and wavelength modulation spectroscopy with a continuous-wave quantum cascade laser in the mid-infrared region. The heterogeneous reactions of NO2(g) with water in the presence of 20 mM KI, 20 mM NaBr or 100 mM NaClO4 have been investigated by direct monitoring of HONO(g) in the gas phase. The formation of HONO(g) was decreased by addition of KI or NaClO4, while NaBr have little effect on the formation of HONO(g).

通过使用空腔响起的光谱和波长调制光谱法与中膜中部区域中的连续波量子级联激光器，开发了基于激光的气态亚硝酸的仪器。 No2（G）在20 mM Ki，20 mM NABR或100 mM NACLO4的情况下与水的异质反应已通过在气相中直接监测HONO（G）进行了研究。通过添加Ki或NaClo4减少了Hono（G）的形成，而NABR对HONO（G）的形成几乎没有影响。

项目成果

Conversion of gaseous nitrogen dioxide to nitrate and nitrite on aqueous surfactants

• DOI: 10.1039/c0cp01497d
• 发表时间: 2011-01-01
• 期刊: PHYSICAL CHEMISTRY CHEMICAL PHYSICS
• 影响因子: 3.3
• 作者: Kinugawa, Takashi;Enami, Shinichi;Colussi, Agustin J.
• 通讯作者: Colussi, Agustin J.

Iodine emission from the heterogenious reactions of gaseous nitrogen dioxide with aqueous iodide

气态二氧化氮与碘化物水溶液的多相反应产生的碘排放

• 发表时间: 2011
• 作者: 薮下彰啓;中野幸夫;定森健悟;石渡孝;川崎昌博
• 通讯作者: 川崎昌博

Known unknowns explained: HONO daytime production from the anion-catalyzed uptake of NO2 on secondary organic aerosol

已知的未知数解释：HONO 白天通过二次有机气溶胶阴离子催化吸收 NO2 产生

• 发表时间: 2012
• 作者: Agustin J. Colussi;Akihiro Yabushita;Shinichi Enami;Michael R. Hoffmann;Wei-Guang Liu;Himanshu Mishra;William A. Goddard;III
• 通讯作者: III