Structural and magnetochemical investigations into spin-spin exchange couplings in homo- and heteronuclear d-f complexes

同核和异核 d-f 配合物中自旋-自旋交换耦合的结构和磁化学研究

• 批准号: 5368662
• 负责人: Professor Dr. Heiko Lueken (†)
• 金额: --
• 依托单位: Institut für Anorganische Chemie (IAC)
• 依托单位国家: 德国
• 项目类别: Priority Programmes
• 财政年份: 2002
• 资助国家: 德国
• 起止时间: 2001-12-31 至 2009-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/5368662?language=en
• 关键词: Structural; magnetochemical; investigations; into; spin

In the preparative part of the project organometallic europium(II) andgadolinium(III) species will be combined with reactive organometallictransition metal molecules. The former systems comprise di- andtricyclopentadienides, whereas the latter systems consist ofparamagnetic transition metal cyclopentadienyl halides. Theinvestigations are of interest with respect to the exchange pathwaylanthanide--halogen--transition metal. In the theoretical part of the project the computer program formagnetochemical analysis of homodinuclear transition metal andlanthanide compounds will be extended with regard to the heteronuclearsystems under investigation.

在项目的制备部分中，有机金属欧洲（II）和gadolinium（III）物种将与反应性有机金属分子结合使用。前一个系统包含二环腺苷，而后者的系统由Paramagnetic Transition Metal CyclopentadaDienyl卤化物组成。对交换途径隆望尼（北甲硅原） - 转换金属是感兴趣的。在项目的理论部分中，计算机程序对均核过渡金属和伦敦尼化合物的型号分析将扩展到正在研究的异核性系统方面。