CHARACTERIZATION OF VISIBLE,TUNABLE SOLID STATE LASER MATERIALS

可见光、可调谐固态激光材料的表征

• 批准号: 07650049
• 负责人: YAMAGA Mitsuo
• 金额: $ 1.47万
• 依托单位: GIFU UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 1995
• 资助国家: 日本
• 起止时间: 1995 至 1996
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07650049/
• 关键词: SOLID STATE LASER; TUNABLE LASER; TRANSITION METAL IONS; RARE-EARTH IONS; OXIDES; DISORDER; TITANIUM IONS; CHROMIUM IONS; Cr^<3+>; Ce^<3+>; 可変波長固体レーザー; CaYAlO_4結晶; 可変波長; 酸化物結晶; 不規則置換型結晶; チタニウムイオン; クロムイオン; スペクトロスコピー

Transition metal ions Cr^<3+>, Ti^<3+> and rare earth ions Ce^<3+> in crystals are used as laser active ions. Since electron-phonon couplings of their ground and excited state electrons are quite different, the optical transitions feature broad absorption and emission bands, giving rise to a wide tuning range of laser oscillation. Recently, the demonstrations of optically pumped solid-state tunable lasers obtained from Cr^<3+> : LiCaAlF_6, Ti^<3+> : Al_2O_3, and Ce^<3+> : LiYF_4 crystals at room temperature were reported. In order to obtain new tunable solid state laser materials, we have examined the electronic properties of Cr^<3+>, Ti^<3+>, Ce^<3+> : CaYAlO_4 (CYA) using electron spin resonance (ESR) and optical spectroscopy.ESR studies of Cr^<3+> in CYA show Cr^<3+> ions in sites with ordered and disordered configurations of the second nearest-neighbor Ca^<2+>/Y^<3+> ions, respectively. The polarized intensities of the ^4A_2-^4T_2 absorption band and the R_1-line fluorescence suggest that the CrO_6^<9-> octahedra undergo an angular distortion such that the magnetic z-axis of the spectrum is rotated away from the crystal c-axis.The g tensor of Ce^<3+> in CYA was obtained to be g_<11>=2.6, g_*=1.6. The ESR results indicate that the wavefunction of the ground state of Ce^<3+> in CYA has a dominant component of |J,J_Z>=|5/2,5/2>. The absorption of Ce^<3+> in CYA was observed in the UV region (200-370nm) and the luminescence band has a peak at 490nm.

晶体中的过渡金属离子Cr 3+ 、Ti 3+ 和稀土离子Ce 3+ 用作激光活性离子。由于基态电子和激发态电子的电子-声子耦合有很大不同，光学跃迁具有较宽的吸收带和发射带，从而产生较宽的激光振荡调谐范围。最近，报道了室温下由Cr^<3+>：LiCaAlF_6、Ti^<3+>：Al_2O_3和Ce^<3+>：LiYF_4晶体获得的光泵浦固态可调谐激光器的演示。为了获得新型可调谐固态激光材料，我们利用电子自旋共振（ESR）研究了Cr^<3+>、Ti^<3+>、Ce^<3+> : CaYAlO_4 (CYA)的电子性质CYA 中 Cr^<3+> 的 ESR 研究显示 Cr^<3+> 离子位于第二近邻 Ca^<2+>/Y^<3+> 有序和无序构型的位点离子，分别。 ^4A_2-^4T_2 吸收带和 R_1 线荧光的偏振强度表明 CrO_6^<9-> 八面体发生角度畸变，使得光谱的磁 z 轴旋转远离晶体 c-得到CYA中Ce^3+的g张量为g_<11>=2.6，g_*=1.6。 ESR结果表明CYA中Ce^<3+>基态波函数的主导成分为|J,J_Z>=|5/2,5/2>。在UV区(200-370nm)观察到CYA中Ce 3+ 的吸收并且发光带在490nm处具有峰值。

项目成果

M.Yamaga et al (他8人): "A Study of Substitutional disorder in Cr^ : CaYAlO_4 : II. Electron spin resonance and polarization of optical spectra" J.Phys. : Condensed Matter. 8. 10633-10646 (1996)

M. Yamaga 等人（其他 8 人）：“Cr^3+ 中取代无序的研究：CaYAlO_4：II。电子自旋共振和光谱偏振”J.Phys：凝聚态物质。 (1996)

M.Yamaga et.al (他5人): "A Study of Substitutional disorder in Cr^ : CaYAlO_4 : I.Fluorescence line narrowing" J.Phys. : Condensed Matter. 8. 3487-3503 (1996)

M.Yamaga 等人（其他 5 人）：“Cr^3+ 中替代紊乱的研究：CaYAlO_4：I.荧光谱线变窄”J.Phys：Condensed Matter（凝聚态物质）。

Mitsuo Yamaga, Peter I Macfarlane, Keith Holliday, Brain Henderson, Nobuhiro Kodama, and Yuka Inoue: "A study of substitutional disorder in Cr^ : CaYAlO_4 : I.Fluorescence line narrowing" J.Phys. : Condens. Matter. 8. 3487-3503 (1996)

Mitsuo Yamaga、Peter I Macfarlane、Keith Holliday、Brain Henderson、Nobuhiro Kodama 和 Yuka Inoue：“Cr^<3 > 中替代性紊乱的研究：CaYAlO_4：I.荧光谱线变窄” J.Phys。

N Kodama, M Yamaga and B Henderson: "Inhomogeneous broadening of the Ce^ luminescence in CaYAlO_4" J.Phys. : Condens. Matter. 8. 3505-3512 (1996)

N Kodama、M Yamaga 和 B Henderson：“CaYAlO_4 中 Ce^3 > 发光的不均匀展宽”J.Phys。

M.Yamaga, P.I.Macfarlane, Keith Holliday, B.Henderson, N.Kodama, and Y Inoue: "A study of exchange interaction in Cr^-doped CaY_Gd_xAlO_4" J.Phys. : Condens. Matter. 9. 1575-1584 (1997)

M.Yamaga、P.I.Macfarlane、Keith Holliday、B.Henderson、N.Kodama 和 Y Inoue：“Cr^<3> 掺杂 CaY_<1-x>Gd_xAlO_4 中交换相互作用的研究”J.Phys。