Development of well-orderd organizations using self-organized electroactive polymers

使用自组织电活性聚合物开发有序组织

• 批准号: 12650888
• 负责人: RIKUKAWA Masahiro
• 金额: $ 1.66万
• 依托单位: Sophia University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2000
• 资助国家: 日本
• 起止时间: 2000 至 2001
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12650888/
• 关键词: Well-organized structure; Polythiophene; Electrostatic interaction; Self-assembly films; Conducting polymer; 1-D wire; Band gap; Third-order optical non-linearity; 自己組織性; 立体規則性; Langmuir-Blodgett法; 光学特性; 電気特性; 組織化

1) Synthesis of self-organized polymers by novel polymerization methodNovel regiocontrolled polythiophene derivatives could be synthesized in this research project. In addition, polyaniline microspheres in sub-micrometer order diameter were prepared by the polymerization method developed by our group.2) Study on self-organization behavior and structuresThe relationship between self-organization and regioregularity for regiocontrolled polymers was investigated by using X-ray diffraction measurements. The regioregularity for regiocontrolled polymers induces the self-organization.3) Preparation of ultra thin films and self-organizationUltra thin films of regiocontrolled polymers were fabricated by Langmuir-Blodgett method. These dipping processes improved the self-organization of ultra thin films. Self-assembly films of these polymers were also prepared by the electrostatic interaction between polycations and polyanions.4) Investigation of electrical and optical properties for self-organized materialsThe self-organization and well-defined structures result in higher electrical conductivity and low band gaps for self-organized materials.

1）新型聚合方法合成自组织聚合物本研究项目可以合成新型区域控制的聚噻吩衍生物。此外，采用本课题组开发的聚合方法制备了亚微米级直径的聚苯胺微球。2）自组织行为和结构研究利用X射线衍射研究了区域可控聚合物的自组织与区域规整性之间的关系。测量。区域控制聚合物的区域规整性诱导了自组织。3）超薄膜的制备和自组织采用Langmuir-Blodgett法制备了区域控制聚合物超薄膜。这些浸渍工艺改善了超薄膜的自组织性。这些聚合物的自组装薄膜也是通过聚阳离子和聚阴离子之间的静电相互作用制备的。4）自组织材料的电学和光学性质的研究自组织和明确的结构导致了更高的电导率和低带隙。自组织材料。

项目成果

Y. Tabuehi: "Incorporation of conjugated polydiacetylene systems into organic-inorganic quantum-well structures"Chem. Commun. 2592-2593 (2001)

Y. Tabuehi：“将共轭聚二乙炔系统纳入有机-无机量子阱结构”Chem。

M. Kaneto: "Photovoltaic cell using high mobility poly(alkylthiophene)s and TiO_2"Synthetic Metals. 121. 1537-1538 (2001)

M. Kaneto：“使用高迁移率聚（烷基噻吩）和 TiO_2 的光伏电池”合成金属。

Y.Tabuchi: "Incorporation of conjugated polydiacetylene systems into organic-inorganic quantum-well structures"Chem.Commun. 2592-2593 (2001)

Y.Tabuchi：“将共轭聚二乙炔系统纳入有机-无机量子阱结构”Chem.Commun。

K.Kaneto: "Alkyl chain length dependence of Field-Effect mobilities in regioregular poly(3-alkyltniophene)"Jpn.J.Appl.Phys.. 39. L872-L874 (2000)

K.Kaneto：“区域规则性聚（3-烷基噻吩）中场效应迁移率的烷基链长度依赖性”Jpn.J.Appl.Phys.. 39.L872-L874（2000）

W.Takashima: "Effects of regioregularity on carrier transport in poly(alkylthiophene)films with various alkyl chain lengths"Current Applied Physics. 1. 90-97 (2001)

W.Takashima：“区域规整性对具有不同烷基链长度的聚（烷基噻吩）薄膜中载流子传输的影响”当前应用物理学。