Evaluation of Overall Greenness of Solid-Acid Catalyzed Processes

固体酸催化工艺的整体绿色度评价

• 批准号: 12650781
• 负责人: MISONO Makoto
• 金额: $ 2.24万
• 依托单位: Kogakuin University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2000
• 资助国家: 日本
• 起止时间: 2000 至 2001
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12650781/
• 关键词: Heteropolyacid; Solid acid catalyst; Pseudoliquid; Transient-response method; Solid-state NMR; Hydrogen bond; Acidic proton; Methyl t-butyl ether; 固体酸; グリーン触媒; 触媒プロセス; ライフサイクルアセスメント; ゼオライト; アミン合成

Investigating the method for the evaluation of greenness of chemical synthetic processes, the following results have been obtained.1. Quantitative evaluation of greenness of solid-acid catalyzed process.After listing up the items necessary for the evaluation, the inventory data have been collected. The existing methods for the evaluation of greenness such as eco-efficiency were also surveyed. The E-factor for reactions like Beckmann rearrangement catalyzed by a solid acid were estimated2. Experimental studies were also carried out for catalytic processes with the discussion of their greenness.The examples are Beckmann rearrangement with porous aluminosilicates, synthesis of pyroridine form butanediol, new solid acids usable in water, and heteropolyarids for selective oxygenation3. Inventory data for the estimation of greenness were collected and a trial of the evaluation was made.

研究化学合成过程绿色的方法，获得了以下结果。1。固体催化过程的绿色度的定量评估。列出评估所需的项目后，已收集库存数据。还调查了评估绿色（例如生态效率）的现有方法。估计了固体酸催化的贝克曼重排等反应的电子因素2。还通过讨论其绿色进行了实验研究进行催化过程。例子是贝克曼（Beckmann）与多孔氧化铝硅酸盐的重排，吡啶二醇的合成丁二醇的合成，可在水中使用的新固体酸，以及用于选择性氧气的杂质果果3。收集了估计绿色的库存数据，并进行了评估试验。

项目成果

御園生 誠: "グリーンケミストリーの目指すものと触媒の課題"触媒. 43(1). 7-11 (2001)

Makoto Misono：“绿色化学的目标和催化剂的挑战”Catalyst 43(1)。

Z. Hou et al.: "Synthesis of Diphenylmethane from Formalin and Benzene in a Biphasic System with 12-Tungstophophoric Acid"Chem. Commun.. 1686-1687 (2001)

Z. Hou等人：“在双相系统中用12-钨磷酸从福尔马林和苯合成二苯甲烷”Chem。

御園生誠(監修): "環境触媒とグリーンケミストリー"シーエムシー出版. 306 (2000)

Makoto Misono（导师）：“环境催化剂和绿色化学”CMC Publishing 306（2000）。

Y. Nishiyama et al.: "High Turnover Numbers for the Catalytic Selective epoxidation of Alkenes with 1 atm of Molecular Oxygen"Angew. Chem.. 19. 3639-3641 (2001)

Y. Nishiyama 等人：“1 atm 分子氧催化选择性环氧化烯烃的高周转数”Angew。

M.Misono: "Unique Acid Catalysis of Heteropoly Compounds(Heteropolyoxometalates)in the Solid State"Chem.Commun.. 1141-1152 (2001)

M.Misono：“固态杂多化合物（杂多金属氧酸盐）的独特酸催化”Chem.Commun.1141-1152（2001）