Newly Preparation of Chaotic Low Dimensional Conducting System by Polymer C60 Ultrathin films and Application to Super-functional Electronic Devices

聚合物C60超薄膜混沌低维导电体系的新制备及其在超功能电子器件中的应用

• 批准号: 12650322
• 负责人: YAMAMOTO Hiroshi
• 金额: $ 2.11万
• 依托单位: Nihon University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2000
• 资助国家: 日本
• 起止时间: 2000 至 2002
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12650322/
• 关键词: C60 Derivatives; Self-Assembly Monolayer; Atomic Force Microscopy; MgO; Resistivity Anomaly; 室温超電導; 電子間力顕微鏡; 室温超伝導; C_<60>; 超薄膜; 低次元; エピタキシャル; 超伝導; FET; C60; 真空蒸着法; 2次元成長; 極微細ファイバー; AFM

The purpose of this work are the following:1) The synthesis of the novel 2-dimensional conducting system on the basis of the interaction between metals and π electrons by using the self-assembly monolayer formed on the Au ultrathin films.2) The investigation of the chaotic conducting system and the possibility of a room temperature superconductivity.As results of this work are the following:1) We have developed the new process to prepare the C60 derivative (C60-O-C8SH) self-assembly monolayer (C60-SAM) on Au ultrathin films/MgO(100)single crystal.2) By AFM observation we demonstrated that nano-scale Au ultrathin films were prepared along to the steps formed of the clear step and terrace structures were fabricated by optimization of the annealing conditions. The obtained samples, C60-SAM/Au/MgO were the materials system corresponding to the room temperature superconductor model proposed by Little and Ginzburg.3) In some of the obtained samples the resistivity anomaly was observed at about 200K, when the micro-scale electrodes were fabricated for the resistivity measurements.These obtained results revealed the possibility of the room temperature superconductivity which will be clarified by the refinement of the sample preparation process and/or the detailed measurements of the sample characterization.

这项工作的目的如下：1）通过使用金属与π电子之间的相互作用，使用在AU超薄膜上形成的自组装单层来合成新颖的二维导电系统。2）混乱的导电系统的投资。 （C60-O-C8SH）AFM观察结果通过AU Ultrathin膜/MGO（100）单晶2）上的自组装单层（C60-SAM），我们证明，通过最佳化制造了纳米级Au Ultrathin膜，该纳米级AU超薄膜是通过确定的确定条件制造的。获得的样品C60-SAM/AU/MGO是与Little和Ginzburg提出的室温超导体模型相对应的材料系统。样品制备过程和/或样品表征的详细测量值。

项目成果

M.Ohkubo, K.Fukai, N.Iwata, H.Yamamoto: "Preparations of conductive ReO3 thin films"Superconductor Science and Technology (SuST). Vol.15,No.12. 1778-1780 (2002)

M.Ohkubo、K.Fukai、N.Iwata、H.Yamamoto：“导电 ReO3 薄膜的制备”超导科学与技术 (SuST)。

H.Yamamoto et al.: "Preparation of Self-Assembly Monolayer by C60 Derivatives"Trans. of the Materials Research Society of Japan. 25・2. 413-416 (2000)

H. Yamamoto 等人：“C60 衍生物的自组装单分子层的制备”，日本材料研究会 25・2（2000 年）。

N.Iwata, N.Hashimoto, H.Yamamoto: "Preparation of Continuous C60 Thin Films with Flat Surfaces by Vacuum Evaporation"Trans.of the MRS-J. Vol.26,No.4. 1339-1342 (2001)

N.Iwata、N.Hashimoto、H.Yamamoto：“通过真空蒸发制备具有平坦表面的连续 C60 薄膜”Trans. of the MRS-J。

N. Iwata, H. Okuyama, S. Kuroda, Y. Shimizu, H. Imai and H. Yamamoto: "Preparation of Continuous C60 Thin Films with Flat Surfaces by Vacuum Evaporation"Trans. of the MRS-J. Vol. 26, No. 4. 1339-1342 (2001)

N. Iwata、H. Okuyama、S. Kuroda、Y. Shimizu、H. Imai 和 H. Yamamoto：“通过真空蒸发制备具有平坦表面的连续 C60 薄膜”Trans。

K.Suzuki, M.Okamoto, S.Alsadoon, N.Iwata, H.Yamamoto: "Chromogenic properties of Phthalocyanine Derivatives Langmuir-Blodgett Films"Trans. Mate. Res. Soc. Jpn.. Vol.27,NO.2. 345-348 (2002)

K.Suzuki、M.Okamoto、S.Alsadoon、N.Iwata、H.Yamamoto：“酞菁衍生物 Langmuir-Blodgett 薄膜的显色特性”Trans。