FUNCTION CREATION OF ELECTROPOLYMERIZED CONDUCTIVE POLYMERS AND THEIR APPLICATION TO HIGH DENSITY SECONDARY BATTERY

电聚合导电聚合物的功能创造及其在高密度二次电池中的应用

• 批准号: 03650664
• 负责人: OSAKA Tetsuya
• 金额: $ 1.22万
• 依托单位: WASEDA UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (C)
• 财政年份: 1991
• 资助国家: 日本
• 起止时间: 1991 至 1992
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-03650664/
• 关键词: ELECTROPOLYMERIZED POLYMER; HIGH DENSITY BATTERY; MIM DEVICE; POLYMER BATTERY; ポリマ-電池

WASEDA UNIVERSITYFrom these research on electropolymerized conductive polymers, we summarize the following results.(1) For the application to lithium batteries, the cathode materials composed of polyaniline-polypyrrole multilayer and n-type PPy(polypyrrole)/Pss(polystylene sulfonate) composite were de-signed and it worked for 3V level lithium battery. Moreover, the all solid state lithium battery of Li/PEO-LiC104/PPy was tried to evaluate for high energy density battery.(2) The switching MIM device for LCD driving was proposed to use electropolymerized non-conducting polymer, where MIM is metal(ITO)-insulator(Polymer)-metal(ITO) system. The electropolymetization conditions for making insulator polymers were studied and the polymers were formed until a certain thickness (eg. 0.2 mum) in NaOH, NaHCO or Na CO electrolyte solution. The MIM device showed symmetrical non-linear response and worked for switching device for LCD.(3) The application of the MIM device shown in (2) term to the micro-pH sensor was studied. The insulator polymer responses to very small solution, especially OH pH sensor when added the voltage near the threshold voltage.

WASEDA UNIVERSITYFrom these research on electropolymerized conductive polymers, we summarize the following results.(1) For the application to lithium batteries, the cathode materials composed of polyaniline-polypyrrole multilayer and n-type PPy(polypyrrole)/Pss(polystylene sulfonate) composite were de-signed and it worked for 3V level lithium battery.此外，试图评估LI/PEO-LIC104/PPY的所有固态锂电池，以评估高能密度电池。（2）建议使用用于LCD驱动的开关MIM设备使用电聚糖非导向聚合物，其中MIM是MIM是金属（ITO） - iTO（ITO） - METAL（ITO） - 仪器（Polimenter（Polymer） - Metal（Poliment） - Metal（ITAL（ITAL））系统。研究了制造绝缘聚合物的电分析条件，并形成聚合物，直到NaOH，Nahco或Na Co电解质溶液中的一定厚度（例如0.2 MUM）。 MIM设备显示对称的非线性响应，并用于用于LCD的开关设备。（3）研究了（2）项中显示在微pH传感器中的MIM设备的应用。绝缘子聚合物对非常小的溶液的响应，尤其是当在阈值电压附近添加电压时，尤其是OH pH传感器。

项目成果

逢坂 哲彌、門間 聰之: "ポリマー二次電池とその基礎特性評価" 電気化学. 60. 369-375 (1992)

Tetsuya Osaka、Tomoyuki Monma：“聚合物二次电池及其基本表征”电化学 60. 369-375 (1992)。

T.Osaka, T.Fukuda, K.Ouchi, T.Momma: "Conduction Mechanism in Indium Tin Oxide/Electroinactive Polypyrrole/Indium Tin Oxide Sandwich Structures" Thin Solid Films. Vol.215. 200-202 (1992)

T.Osaka、T.Fukuda、K.Ouchi、T.Momma：“氧化铟锡/电化学聚吡咯/氧化铟锡三明治结构的传导机制”固体薄膜。

T.Osaka: "Electropolymerization of Electroinactive Polypyrrole Film for a Nonlinear MIM Switching Device" Denki Kagaku. Vol.59-12. 1019-1025 (1991)

T.Osaka：“用于非线性 MIM 开关器件的电惰性聚吡咯薄膜的电聚合”Denki Kagaku。

T.Nakajima: "LCD Driving Characteristics of MIM Diode Using Electropolymerized Polypyrrole Thin Film as an Insulator" Denki Kagaku. 59-12. 1074-1076 (1991)

T.Nakajima：“使用电聚合聚吡咯薄膜作为绝缘体的 MIM 二极管的 LCD 驱动特性”电气化学。

T.Osaka: "Electrochemical Aspects of Advanced Electronic Materials" Electrochimica Acta. 37. 989-995 (1992)

T.Osaka：“先进电子材料的电化学方面”Electrochimica Acta。