Syntheses of New Polynuclear and Low-Dimensional Metal Complexes and Chemical Consequences of Metal Ion Assemblage

新型多核低维金属配合物的合成及金属离子聚集的化学后果

• 批准号: 02303006
• 负责人: ITO Tasuku
• 金额: $ 5.63万
• 依托单位: TOHOKU UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Co-operative Research (A)
• 财政年份: 1990
• 资助国家: 日本
• 起止时间: 1990 至 1992
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-02303006/
• 关键词: Polynuclear Metal Complex; Metal cluster Complex; Low-dimensional Compound; 錯体集合体; 低次錯体; 金属クラスタ-錯体; 一次元錯体

A total of 19 scientific members of the research group have worked on the titled research project for three years.Research results have been reported in a separate booklet(225 pages).

该研究小组共有19名科学成员，已在该研究项目上工作了三年。研究结果已在单独的小册子（225页）中报道。

项目成果

K.Mashima: "Rational Preparation and Characterization of a Tandem Tetrametal Clusters. Crystal Structure of Tetrakis(6-di-phenylphosphino-2-pyridonato)dimolybdenum" Chem.Lett.185-188 (1992)

K.Mashima：“串联四金属簇的合理制备和表征。四（6-二苯基膦基-2-吡啶酮）二钼的晶体结构”Chem.Lett.185-188（1992）

K.Umakishi,A.Ichimura,I.Kinoshita,and S.Ooi: "The Dinuclear Palladium(II)Complex of Pyridine-2-thiol.synthesis,Structure and Electrochemistry" Inorg.Chem.,. 29. 4005-4010 (1990)

K.Umakishi、A.Ichimura、I.Kinoshita 和 S.Ooi：“吡啶-2-硫醇的双核钯 (II) 配合物的合成、结构和电化学”Inorg.Chem.,。

K.Tsuge,S.Yajima,H.Imoto,T.Saito: "Synthesis of an Equilateral Triangular Molybdenum Cluster Complex[Mo_3(μ_3-S)_2(μ-S)_3(PMe_3)_6]with Eight Cluster Valence Electrons" J.Am.Chem.Soc.,. 114. 7910-7912 (1992)

K.Tsuge、S.Yajima、H.Imoto、T.Saito：“具有八簇价电子的等边三角形钼簇络合物[Mo_3(μ_3-S)_2(μ-S)_3(PMe_3)_6]的合成”美国化学学会杂志，114。7910-7912 (1992)

M.Kawano,C.Hoshino,and K.Matsumoto: "Synthesis, Properties and Crystal Structure of a Novel mu-Hydragine-Bridged Mixed-Valonce Rutenium(II,III) Complex Stabilized by Hydrazine Hydrogen Bonds, [RuCl(TMP)_2]_2(mu-Cl)(mu-N_2H_4)(mu-S_2)(TMP=P(OMe)_3)" Inorg.

M.Kawano、C.Hoshino 和 K.Matsumoto：“由肼氢键稳定的新型 mu 氢桥混合价钌 (II,III) 配合物的合成、性质和晶体结构，[RuCl(TMP)_2”

M.Suzuki,Y.Hayashi,K.Munezawa,M.Suenaga,H.Senda,and A.Uehara: "Synthesis and Characterization of a Novel Dimer of Di(μ-oxo)manganese Dimers with Two Coordinated Water Molecules in(III,IV,III,IV)Oxidation State" Chem.Lett,. 1229-1932 (1991)

M. Suzuki、Y. Hayashi、K. Munezawa、M. Suenaga、H. Senda 和 A. Uehara：“具有两个配位水分子的二（μ-氧代）锰二聚体的新型二聚体（III）的合成和表征,IV,III,IV) 氧化态" Chem.Lett,. 1229-1932 (1991)