CAREER: Epitaxial stabilization of non-perovskite oxide quantum materials

职业：非钙钛矿氧化物量子材料的外延稳定

• 批准号: 2339913
• 负责人: Julia Mundy
• 金额: $ 78.66万
• 依托单位: Harvard University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2024
• 资助国家: 美国
• 起止时间: 2024-01-15 至 2028-12-31
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2339913&HistoricalAwards=false
• 关键词: CAREER; Epitaxial; stabilization; non; perovskite

Non-Technical abstract: Quantum mechanics determines the properties of all materials at the finest length scales. There exist some materials, however, where the quantum nature transcends from the microscopic to the macroscopic and in doing so produces incredible phenomena. These so-called quantum materials have the potential to revolutionize a number of fields, in applications ranging from low-energy computing to dissipationless current flow. Further advances in this field require the design and discovery of novel quantum materials with enhanced functionality. The research team will synthesize a new family of quantum materials that have not been made previously and probe the atomic structure of these compounds. The team will also develop an elementary science curriculum for a dual language program and support first-generation and low-income undergraduate researchers.Technical Abstract: Complex oxides display some of the most exotic physical states known, with phenomena as diverse as high-temperature superconductivity and ferromagnetism. To date, however, much of the work on complex oxides thin films and heterostructures has focused on the perovskite oxides. Here the research team seeks to develop the synthesis and characterization of a distinct set of oxide materials which could display additional emergent phenomena not present in the perovskite oxides. The materials will be synthesized with reactive oxide molecular-beam epitaxy, allowing exquisite control over the deposited structures. The project will study emergent superconductivity in LiTi2O4 as well as heavy fermion, spin-polarized and possible topological compounds. The materials will be investigated by bulk and proximal probes to map out the atomic lattice structure, band structure and spin fluctuations to correlate with macroscopic properties. Combined this activity will provide rich insight into a fascinating class of emergent materials.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术摘要：量子力学确定所有材料在最大长度尺度上的性质。然而，存在一些材料，其中量子性质从微观到宏观的超越，并产生令人难以置信的现象。这些所谓的量子材料有可能彻底改变许多字段，从低能计算到无耗散电流流量。该领域的进一步进步需要设计和发现具有增强功能的新型量子材料。研究团队将合成以前未制成的新量子材料家族，并探测这些化合物的原子结构。 该团队还将为双语言课程开发基础科学课程，并支持第一代和低收入本科研究人员。技术摘要：复杂的氧化物展示了一些已知的最奇特的物理状态，其现象是高温超导性的多样化的现象和铁磁性。然而，迄今为止，关于复杂氧化物薄膜和异质结构的许多工作都集中在钙钛矿氧化物上。在这里，研究小组试图开发一组不同的氧化物材料的合成和表征，这些氧化物材料可能显示出钙钛矿氧化物中不存在的其他新兴现象。 这些材料将与反应性氧化物分子梁外延合成，从而可以对沉积结构进行精致的控制。 该项目将研究LITI2O4的新兴超导性，以及重型费米，自旋偏振和可能的拓扑化合物。 该材料将通过批量和近端探针进行研究，以绘制原子晶格结构，带结构和自旋波动，以与宏观特性相关。这项活动的结合将为一类引人入胜的新兴材料提供丰富的见解。该奖项反映了NSF的法定使命，并被认为是值得通过基金会的知识分子优点和更广泛的影响审查标准的评估来支持的。