NSF-PREM: Center for Interfacial Electrochemistry of Energy Materials (CiE2M)

NSF-PREM：能源材料界面电化学中心 (CiE2M)

• 批准号: 1827622
• 负责人: Jorge Colón
• 金额: $ 390万
• 依托单位: University of Puerto Rico-Rio Piedras
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-09-01 至 2024-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1827622&HistoricalAwards=false
• 关键词: NSF; PREM; Center; Interfacial; Electrochemistry

Non-Technical Summary:The University of Puerto Rico, Rio Piedras Campus (UPRRP), Universidad Metropolitana (UMET) and Universidad del Turabo (UT), all located in Puerto Rico and Hispanic Serving Institutions (HSI), and the Cornell High Energy Synchrotron Source (CHESS) have teamed up in this educational and innovative collaborative materials research effort to bring together and develop a diverse and talented scientific interdisciplinary community with expertise in operando synchrotron X-ray techniques to enhance energy storage and conversion devices. In this collaborative effort, graduate and undergraduate students will perform research at their home institutions and at CHESS, to study the electrochemical processes associated with energy conversion and storage technologies. This Partnership in Research and Education for Materials (PREM) project will impact participating students' education by offering new tailored courses in their curriculum, and by developing workshops and making training opportunities available to them in strong collaboration with CHESS. The results of this research and educational partnership among UPR-UMET-UT-CHESS will be disseminated in publications in peer-reviewed journals and conference presentations. Workshops and synchrotron hands-on activities will also be developed for K-12 students to motivate their interest in energy-based technologies and as well as the use of high-energy X-ray synchrotron techniques through close interactions and collaborations with CHESS.Technical Summary:This collaborative effort brings the synergistic expertise of a diverse group of scientists to address fundamental issues related to electrochemical energy storage and conversion devices. The project is led by Dr. Carlos R. Cabrera, from the Department of Chemistry at UPRRP, and Dr. Joel D. Brock, Director of CHESS at Cornell University. The collaborative efforts among UPRRP, UMET, UT and CHESS are spread over three interdisciplinary research groups (IRGs). Each IRG will embrace the use of unique, yet complementary, strategies related to energy conversion and storage and synchrotron based techniques:IRG 1. Nanostructured electrocatalytic materials: To develop a fundamental understanding of the processes that govern reactivity at the interface of alkaline fuel cells by combining efforts in materials chemistry and fundamental electrochemistry along with operando X-ray techniques;IRG 2. Nanostructured materials for dye-sensitized solar cells (DSSCs): Establish a fundamental understanding of structural changes of DSSCs under operando conditions, by X-ray absorption studies; andIRG 3. Porous nanostructured materials for energy storage: Develop a state-of-the-art protocol for electrolyte nano-confinement effects, electrode structural changes upon intercalation, and for the interfacial electrochemical energy transfer mechanism in composite electrode materials.This collaborative team will organize conference meetings at UPR and at CHESS to enable participants to present their research findings and to establish new innovative ideas to increase our understanding of interfacial electrochemical processes associated with energy conversion and storage technologies. Regular meetings will enable participating students to develop as a workforce on energy materials using synchrotron-based techniques.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

Non-Technical Summary:The University of Puerto Rico, Rio Piedras Campus (UPRRP), Universidad Metropolitana (UMET) and Universidad del Turabo (UT), all located in Puerto Rico and Hispanic Serving Institutions (HSI), and the Cornell High Energy Synchrotron Source (CHESS) have teamed up in this educational and innovative collaborative materials research effort to bring共同开发一个具有多样化和才华横溢的科学跨学科社区，具有Operando Synchrotron X射线技术的专业知识，以增强能源的存储和转换设备。在这项合作的努力中，研究生和本科生将在其家庭机构和国际象棋中进行研究，以研究与能量转换和存储技术相关的电化学过程。 材料研究和教育的这种合作伙伴关系（PERM）项目将通过提供课程中的新量身定制课程，开发研讨会并为他们提供与国际象棋的强有力合作，从而影响参与学生的教育。 Upr-Umet-UT-Chess之间的这项研究和教育合作伙伴关系的结果将在经过同行评审的期刊和会议演讲中的出版物中传播。 还将为K-12学生开发研讨会和同步动手活动，以激励他们对基于能量的技术以及使用高能X射线同步技术的使用以及通过与国际象棋的紧密互动和合作来进行技术汇总：这一合作能力使能源集团的相互启发性地与各种各样的科学问题相关方面的交往来宣布各种各样的问题，从而使筹集的相关性与宗教相关方面的范围相互促进，从而使他们与Chess.tecome forsection deacsrone decroseconconconsoce decrode versoctros versoctros conversone versoctros conversone decrodrosection： 该项目由UPRP化学系的Carlos R. Cabrera博士和康奈尔大学国际象棋主任Joel D. Brock博士领导。 UPRRP，UMET，UT和国际象棋之间的合作努力分布在三个跨学科研究小组（IRGS）上。 每个IRG都将接受与能量转换和存储相关的独特但互补的策略的使用，以及基于同步的技术：IRG 1。纳米结构的电催化材料：以对碱性化学和基本材料中的材料中的材料中的努力和基本材料相结合的Oprantory forge forge forgiquiquiquiquiquiquiquiquique x-ray Irgay x-ray x-ray x-ray x-ray x-ray x-ray Irgay x-ray;染料敏化的太阳能电池（DSSC）：通过X射线吸收研究在操作系统条件下对DSSC的结构变化建立基本理解； Andirg 3。用于存储能源的多孔纳米结构材料：为电解质纳米辅助效果，互生时的电极结构变化以及复合电极材料中的界面电化学转移机制的结构变化而制定最先进的协议与能量转换和存储技术相关的界面电化学过程。 常规会议将使参与的学生能够使用基于同步加速器的技术发展作为能源材料的劳动力。该奖项反映了NSF的法定任务，并被认为是值得通过基金会的智力优点和更广泛影响的评估审查标准通过评估来获得支持的。

项目成果

Isolating the Electrocatalytic Activity of a Confined NiFe Motif within Zirconium Phosphate

• DOI: 10.1002/aenm.202003545
• 发表时间: 2021-04-14
• 期刊: ADVANCED ENERGY MATERIALS
• 影响因子: 27.8
• 作者: Sanchez, Joel;Stevens, Michaela Burke;Jaramillo, Thomas F.
• 通讯作者: Jaramillo, Thomas F.

Fabrication of paper-based microfluidic devices using a 3D printer and a commercially-available wax filament

使用 3D 打印机和市售蜡丝制造纸基微流体装置

• DOI: 10.1016/j.talo.2022.100142
• 发表时间: 2022
• 期刊: Talanta Open
• 作者: Espinosa, Antonio;Diaz, Joannes;Vazquez, Edgar;Acosta, Lina;Santiago, Arianna;Cunci, Lisandro
• 通讯作者: Cunci, Lisandro

Enhancing ORR Performance of Bimetallic PdAg Electrocatalysts by Designing Interactions between Pd and Ag

• DOI: 10.1021/acsaem.9b01920
• 发表时间: 2020-03-23
• 期刊: ACS APPLIED ENERGY MATERIALS
• 影响因子: 6.4
• 作者: Betancourt, Luis E.;Rojas-Perez, Arnulfo;Cabrera, Carlos R.
• 通讯作者: Cabrera, Carlos R.

Cobalt porphyrin intercalation into zirconium phosphate layers for electrochemical water oxidation

• DOI: 10.1039/d0se01134g
• 发表时间: 2021-01-21
• 期刊: SUSTAINABLE ENERGY & FUELS
• 影响因子: 5.6
• 作者: Barraza Alvarez, Isabel;Wu, Yanyu;Villagran, Dino
• 通讯作者: Villagran, Dino

RoDSE Synthesized Fine Tailored Au Nanoparticles from Au(X) 4 – (X = Cl – , Br – , and OH – ) on Unsupported Vulcan XC-72R for Ethanol Oxidation Reaction in Alkaline Media

RoDSE 在无支撑 Vulcan XC-72R 上使用 Au(X) 4 –（X = Cl –、Br – 和 OH –）合成精细定制的 Au 纳米颗粒，用于碱性介质中的乙醇氧化反应

• DOI: 10.1021/acsaem.8b01284
• 发表时间: 2018
• 期刊: ACS Applied Energy Materials
• 影响因子: 6.4
• 作者: Betancourt, Luis E.;Ortiz-Rodríguez, Ángel M.;Corchado-García, Juan;Cabrera, Carlos R.
• 通讯作者: Cabrera, Carlos R.