I-Corps: Commercialization of Chirped-Pulse Fourier Transform THz Spectrometers for Gas Analysis

I-Corps：用于气体分析的啁啾脉冲傅里叶变换太赫兹光谱仪的商业化

• 批准号: 1242377
• 负责人: Brooks Pate
• 金额: $ 5万
• 依托单位: University of Virginia Main Campus
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2012
• 资助国家: 美国
• 起止时间: 2012-07-01 至 2012-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1242377&HistoricalAwards=false
• 关键词: Corps; Commercialization; Chirped; Pulse; Fourier

Advances in high-speed digital electronics have enabled a new approach for measuring high-resolution molecular rotational spectra of room-temperature gases. The chirped-pulse Fourier transform (CP-FT) technique improves measurement speeds by about four orders-of-magnitude over the current state-of-the-art. This advance makes it possible to bring the traditional advantages of molecular rotational spectroscopy for multispecies detection and high molecular specificity to applications that require high sample throughput or real-time chemical monitoring. The combination of broad instantaneous frequency coverage and high spectral resolution of the spectroscopic features makes it possible to analyze complex gas mixtures without the need for prior chemical separation (like gas chromatography). This advantage produces lower overall spectrometer operating costs by bypassing the need for consumable chromatography supplies.Molecular rotational spectroscopy identifies molecules through their quantum mechanical frequency spectrum. The rotational spectrum can be measured with high frequency accuracy using precision frequency standards like rubidium clocks. These features provide unsurpassed transferability of measurements from lab-to-lab. Once the spectrum is identified, it can forever be recognized on any other instrument. The next-generation CP-FT spectrometers exploit advances in high-speed digital electronics to achieve exceptionally high data throughput - with spectrum acquisition rates of 2.4 Gs/s now possible. There is the potential to develop a qualitatively new analytical tool for chemical monitoring whose power is amplified by mining all of the spectral data produced by these instruments so that the known catalog of molecular signatures rapidly expands in real time. This concept of a data enabled science driven analytical chemistry technique based on widely deployed and internet-connected CP-FT gas sensors has the potential to revolutionize real-time chemical monitoring in applications across the industrial spectrum.

高速数字电子学的进步使得测量室温气体的高分辨率分子旋转光谱成为可能。啁啾脉冲傅立叶变换 (CP-FT) 技术将测量速度比当前最先进技术提高了约四个数量级。这一进步使得将分子旋转光谱用于多物种检测和高分子特异性的传统优势带入需要高样品通量或实时化学监测的应用中成为可能。广泛的瞬时频率覆盖范围和光谱特征的高光谱分辨率相结合，使得分析复杂的气体混合物成为可能，而无需事先进行化学分离（如气相色谱法）。这一优势无需消耗色谱耗材，从而降低了光谱仪的总体运行成本。分子旋转光谱通过量子力学频谱识别分子。可以使用铷钟等精密频率标准以高精度测量旋转频谱。这些功能提供了无与伦比的实验室间测量可转移性。一旦光谱被识别，它就可以永远在任何其他仪器上被识别。下一代 CP-FT 光谱仪利用高速数字电子技术的进步来实现极高的数据吞吐量 - 现在可以实现 2.4 Gs/s 的光谱采集速率。有潜力开发一种用于化学监测的全新定性分析工具，通过挖掘这些仪器产生的所有光谱数据来放大其能力，从而实时快速扩展已知的分子特征目录。这种基于广泛部署和互联网连接的 CP-FT 气体传感器的数据驱动的科学驱动分析化学技术概念有可能彻底改变整个工业领域应用中的实时化学监测。