Collaborative Research: Preparation of New Organic/Inorganic Hybrid Materials: A Multi-Disciplinary Approach to Integrate Research and Undergraduate Education

合作研究：新型有机/无机杂化材料的制备：整合研究和本科教育的多学科方法

• 批准号: 0714439
• 负责人: Hans-Conrad zur Loye
• 金额: $ 19.5万
• 依托单位: University South Carolina Research Foundation
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2007
• 资助国家: 美国
• 起止时间: 2007-06-15 至 2010-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0714439&HistoricalAwards=false
• 关键词: Collaborative; Research; Preparation; New; Organic

This collarorative award in the Inorganic, Bioinorganic and Organometrallic Chemistry program supports Professors Leroy Peterson at Francis Marion University and Hanno zur Loye at the University of South Carolina to continue reserach focused on two coupled areas of research: 1) the synthesis of new ligands and their incorporation into new mixed-metal organic/inorganic hybrid materials and 2) the investigation of new heterometallic semiconducting frameworks based on polyhalobismuthate and polyhaloplumbate materials. The research builds on preparing metal-pyrazinecarboxylate complexes and using them in the preparation of organic/inorganic framework materials. Pyrazinecarboxylate ligands will be used to prepare metal-containing geometric building blocks that can be: a.) linear-bidentate, b.) bent-bidentate and c.) T-shaped-tridentate. Utilizing equipment at FMU as well as large-scale modern instruments (X-ray diffractometers, TGA, DSC, Mass Spectrometers, SQUID and BET systems) at USC, the student researchers and faculty at FMU will fully characterize their products. Equipment training and workshops will be conducted at USC by Dr. zur Loye on directed supramolecular assembly of organic, inorganic, and/or organometallic modules into functional solidsThe broader impacts of this work are to advance undergraduate research for underrepresented minorities and women, while promoting teaching, training and learning to prepare these students for future graduate studies. The collaboration involves the nurturing of a chemistry culture at Francis Marian University (FMU) that will include participation at local and national chemistry society meetings (poster and oral presentations), the development of an FMU undergraduate chemistry symposium, and the enhancement of the FMU research infrastructure via the creation of a modern materials characterization facility.

这一无机、生物无机和有机化学项目的相关奖项支持弗朗西斯马里恩大学的 Leroy Peterson 教授和南卡罗来纳大学的 Hanno zur Loye 教授继续专注于两个耦合研究领域的研究：1）新配体的合成及其纳入新型混合金属有机/无机杂化材料以及2）基于多卤铋酸盐和的新型异金属半导体框架的研究多卤铅酸材料。 该研究建立在制备金属-吡嗪羧酸盐络合物并将其用于制备有机/无机骨架材料的基础上。 吡嗪羧酸盐配体将用于制备含金属的几何构件，其可以是：a.)线性二齿，b.)弯曲二齿和c.)T形三齿。 利用 FMU 的设备以及 USC 的大型现代仪器（X 射线衍射仪、TGA、DSC、质谱仪、SQUID 和 BET 系统），FMU 的学生研究人员和教师将充分表征他们的产品。 zur Loye 博士将在南加州大学举办关于将有机、无机和/或有机金属模块定向超分子组装成功能固体的设备培训和研讨会这项工作的更广泛影响是推进针对代表性不足的少数族裔和女性的本科生研究，同时促进教学、培训和学习，为这些学生将来的研究生学习做好准备。此次合作涉及在弗朗西斯玛丽安大学 (FMU) 培育化学文化，其中包括参加地方和国家化学学会会议（海报和口头报告）、举办 FMU 本科生化学研讨会以及加强 FMU 研究通过创建现代材料表征设施来改善基础设施。