Acquisition of an FT-IR/FT-Raman Spectrometer to Facilitate the Investigation of Solute-Solvent Interactions in Supercritical Fluids.

购买 FT-IR/FT-Raman 光谱仪以促进超临界流体中溶质-溶剂相互作用的研究。

• 批准号: 0618973
• 负责人: Steven Mayer
• 金额: $ 15万
• 依托单位: University of Portland
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2006
• 资助国家: 美国
• 起止时间: 2006-08-01 至 2009-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0618973&HistoricalAwards=false
• 关键词: Acquisition; FT; IR; Raman; Spectrometer

With support from the Major Research Instrumentation (MRI) Acquisition Program, the Department of Chemistry at the University of Portland will acquire a Fourier Transform Infrared/ Fourier Transform Raman Spectrometer (FT-IR/FT-Raman). The instrument will be used to investigate interactions between solutes and solvents in supercritical fluids. One system to be studied will be Rhodamine B dissolved in the co-solvent system of acetonitrile and supercritical carbon dioxide. Study of other solvent systems and dyes is planned.Infrared and Raman spectroscopy measure the vibrational frequencies of molecules. These frequencies are characteristic of the atoms and how they are connected in a molecule. This analytical tool is a sensitive probe of the structure of the molecules and how the surrounding environment influences them. This can help to better understand how to more efficiently extract dissolved substances, process fuels and chemicals, and improve manufacturing processes using chemicals. The instrument will enhance teaching and research of undergraduates at the University of Portland.

在主要的研究工具（MRI）采集计划的支持下，波特兰大学的化学系将获得傅立叶变换红外/傅立叶变换拉曼光谱仪（FT-IR/ FT-RAMAN）。 该仪器将用于研究超临界流体中溶质与溶剂之间的相互作用。 一个要研究的系统将是羟胺B溶解在乙腈和超临界二氧化碳的共溶系统中。 计划对其他溶剂系统和染料进行研究。在红外和拉曼光谱测量分子的振动频率。 这些频率是原子的特征以及它们如何在分子中连接。 该分析工具是对分子结构以及周围环境如何影响它们的敏感探针。 这可以帮助更好地理解如何更有效地提取溶解的物质，工艺燃料和化学物质，并使用化学品改善制造工艺。 该工具将在波特兰大学增强本科生的教学和研究。