RUI: Organic Chemistry of Hypervalent Compounds

RUI：高价化合物的有机化学

• 批准号: 0101021
• 负责人: Viktor Zhdankin
• 金额: $ 24万
• 依托单位: University of Minnesota-Twin Cities
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2001
• 资助国家: 美国
• 起止时间: 2001-04-15 至 2004-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0101021&HistoricalAwards=false
• 关键词: RUI; Organic; Chemistry; Hypervalent; Compounds

With the support of the Organic and Macromolecular Chemistry Program, Professor Viktor V. Zhdankin, of the Department of Chemistry at the University of Minnesota, Duluth, is exploring the chemistry of hypervalent compounds of iodine and xenon. His studies include the preparation and structural characterization of novel, stable complexes of hypervalent iodine and xenon with chelating nitrogen ligands, a search for catalytic reactions utilizing hypervalent iodine, the development of new oxidizing agents based on benziodazoles, and the preparation, structural study, and exploration of the reactivity of mixed phosphonium-iodonium ylides and imides.With this Research in Undergraduate Institutions award, the Organic and Macromolecular Chemistry Program is supporting the research efforts of Professor Viktor V. Zhdankin, of the Department of Chemistry at the University of Minnesota, Duluth. Through the study of new structural types of compounds containing iodine or xenon, Professor Zhdankin will enhance our understanding of the structure and reactivity of these unusual compounds, develop new reagents and procedures for organic synthesis, and search for new compounds with unusual and useful properties. Undergraduate students from the University of Minnesota, Duluth and from other universities will carry out these studies.

在有机和大​​分子化学计划的支持下，明尼苏达大学德卢斯大学化学系的Viktor V. Zhdankin教授正在探索碘和Xenon高估化合物的化学。他的研究包括与螯合氮配体的新颖，稳定的碘和氙气的制备和结构表征，搜索利用过度碘的催化反应的搜索，基于苯二唑的新氧化剂的发展，苯二唑以及苯二唑，以及制剂，结构性研究和探索的反应。在本科机构奖中，有机和大分子化学计划正在支持明尼苏达大学德卢斯大学化学系的Viktor V. Zhdankin教授的研究工作。通过研究含有碘或氙气的新结构类型的化合物，Zhdankin教授将增强我们对这些异常化合物的结构和反应性的理解，开发有机合成的新试剂和程序，并寻找具有异常和有用特性的新化合物。明尼苏达大学，德卢斯大学和其他大学的本科生将进行这些研究。