Electrochemical Studies of Important Organometallic Compounds in New Types of Electrolytes

新型电解质中重要有机金属化合物的电化学研究

• 批准号: 0092702
• 负责人: William Geiger
• 金额: $ 53.7万
• 依托单位: University of Vermont & State Agricultural College
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2001
• 资助国家: 美国
• 起止时间: 2001-02-15 至 2005-01-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0092702&HistoricalAwards=false
• 关键词: Electrochemical; Studies; Important; Organometallic; Compounds

Professor William Geiger of the University of Vermont is supported by the Analytical and Surface Chemistry program to study organometallic compounds electrochemically in novel electrolytes. Of particular interest are noncoordinating fluoroarylborate anions. These substances afford increased solubilities and conductivities in low-to-medium polarity solvents including fluorous solvents. Work in fluorous solvents is attractive because of possibilities of product/reactant/catalyst separation. There are electrochemical advantages which allow the study of ion-pairing interactions in these systems. The PI also proposes to study rhodium-based complexes electrochemically for the purpose of developing new synthetic pathways. The outcomes of the work will be relevant to many areas including electroanalytical chemistry, materials and sensor development, synthetic and industrial chemistry employing homogeneous inorganic or organometallic catalysis and in efforts to replace toxic organic solvents with environmentally benign substitutes.

佛蒙特大学的William Geiger教授得到了分析和表面化学计划的支持，该计划在新型电解质中研究有机金属化合物。 特别令人感兴趣的是非协调的氟化物阴离子。 这些物质在低到中等的极性溶剂（包括易转溶剂）中提供了增加的溶解度和电导率。 由于产品/反应剂/催化剂分离的可能性，在易流性溶剂中工作具有吸引力。 有电化学优势，可以研究这些系统中的离子配对相互作用。 PI还提议在电化学上研究基于菱形的复合物，以开发新的合成途径。 这项工作的结果将与许多领域有关，包括采用均匀的无机或有机金属催化的材料和传感器开发，合成和工业化学，以及用环境良性替代品代替有毒的有机溶剂的努力。