Synthetic, Catalytic, and solid-State Chemistry of Group 13 Complexes

第 13 族配合物的合成、催化和固态化学

• 批准号: 9816155
• 负责人: David Atwood
• 金额: $ 14万
• 依托单位: University of Kentucky
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1998
• 资助国家: 美国
• 起止时间: 1998-09-15 至 2001-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9816155&HistoricalAwards=false
• 关键词: Synthetic; Catalytic; solid; State; Chemistry

Dr. David A. Atwood, Department of Chemistry, North Dakota State University, Fargo, is supported by the Inorganic, Bioinorganic, and Organometallic Program of the Chemistry Division and by the Experimental Program to Stimulate Competitive Research (EPSCoR) for studies of the chemistry of Group 13 complexes. The fundamental chemistry of cationic, anionic, and neutral complexes will be investigated, which could lead to the development of applications in Lewis acid and Ziegler-Naata catalysis and in nanoparticulate oxide synthesis. The education component of this project integrates teaching with research, and fundamental with applied chemistry through the formation of courses which emphasize synthesis, catalysis and solid-state materials in ways that relate the chemistry to applications and uses in daily life. This project addressses the synthesis of new compounds with Group 13 metal ions such as aluminum and gallium. Synthetic strategies will be developed, and a wide range of molecular and solid-state characterization techniques will be used to study the fundamental chemistry of these systems. Fundamental developments in the chemistry of these systems could lead to applications in catalysis and solid-state materials.

David A. Atwood 博士，法戈市北达科他州立大学化学系，得到化学系无机、生物无机和有机金属项目以及刺激竞争性研究实验项目 (EPSCoR) 的化学研究支持第 13 组复合体。 将研究阳离子、阴离子和中性络合物的基本化学，这可能会导致路易斯酸和齐格勒-纳塔催化以及纳米颗粒氧化物合成中应用的发展。 该项目的教育部分将教学与研究、基础与应用化学相结合，通过开设强调合成、催化和固态材料的课程，将化学与日常生活中的应用和用途联系起来。 该项目致力于用铝和镓等第 13 族金属离子合成新化合物。 将开发合成策略，并使用广泛的分子和固态表征技术来研究这些系统的基础化学。 这些系统化学的基本发展可能会导致其在催化和固态材料中的应用。