Kinetics of Unimolecular and Bimolecular Reactions of Halocarbons

卤代烃的单分子和双分子反应动力学

• 批准号: 9122327
• 负责人: Bert Holmes
• 金额: $ 11.81万
• 依托单位: Lyon College
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1992
• 资助国家: 美国
• 起止时间: 1992-06-01 至 1995-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9122327&HistoricalAwards=false
• 关键词: Kinetics; Unimolecular; Bimolecular; Reactions; Halocarbons

In this project in Experimental Physical Chemistry, sponsored by the Chemistry division, Prof. Holmes (Arkansas College) will investigate mechanisms by which hydrogen halides are eliminated from organic molecules in the gas phase. The work is important both for an improved understanding of elimination reactions in general and because many of the reactions are involved in destruction of atmospheric ozone. In addition, the work will provide strong movivation for undergraduate students towards a career in chemistry. %%% Prof. Holmes (Arkansas College) will elucidate and clarify fundamental reactions of chlorinated molecules in the atmosphere. An improved understanding of this process is urgently needed in order to develop effective strategies for coping with destruction of the ozone layer and for dealing with potential global warming.

在化学部门赞助的实验物理化学项目中，福尔摩斯教授（阿肯色学院）将研究在气相中从有机分子中消除氢卤化物的机制。这项工作对于一般来说的消除反应的理解非常重要，并且因为许多反应都涉及大气臭氧的破坏。此外，这项工作将为本科生迈向化学事业的强大动作。 Holmes教授（阿肯色学院）将阐明和阐明大气中氯化分子的基本反应。迫切需要对这一过程的改进理解，以制定应对臭氧层破坏并处理潜在的全球变暖的有效策略。