Synthesis and Chemistry of Zintl Metal Carbonylates

Zintl金属羰基化物的合成与化学

• 批准号: 9107444
• 负责人: Kenton Whitmire
• 金额: --
• 依托单位: William Marsh Rice University
• 依托单位国家: 美国
• 项目类别: Continuing grant
• 财政年份: 1991
• 资助国家: 美国
• 起止时间: 1991-07-01 至 1994-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9107444&HistoricalAwards=false
• 关键词: Synthesis; Chemistry; Zintl; Metal; Carbonylates

This award is made in the Inorganic, Bioinorganic and Organometallic Chemistry Program in support of the research of Dr. Kenton Whitmire at Rice University. The research deals with the synthesis, structure, and reactivity of main group/transition metal clusters. Work will focus on the heavy main group elements (thallium, indium, lead, tin, bismuth and antimony) clustered with Group VIII transition metals (iron, cobalt, ruthenium and osmium). The goals of the research are to synthesize new metal cluster compounds which will probe the limitations of current bonding theories, to study the reactivity of these complexes with a view to establishing stability and structure/function relationships, and to determine how structure, bonding and reactivity patterns vary as a function of transition metal and main group element. %%% The fundamental interactions of main group elements and transition metals is a topic of considerable importance to chemistry, materials science and catalysis. Main group/transition metal alloys have interesting electronic and magnetic properties while main group element compounds are often used as promoters in commercial catalytic processes.

该奖项是在无机、生物无机和有机金属化学项目中颁发的，旨在支持莱斯大学 Kenton Whitmire 博士的研究。该研究涉及主族/过渡金属簇的合成、结构和反应性。 工作重点是与第 VIII 族过渡金属（铁、钴、钌和锇）聚集的重主族元素（铊、铟、铅、锡、铋和锑）。该研究的目标是合成新的金属簇化合物，探索当前键合理论的局限性，研究这些配合物的反应性，以建立稳定性和结构/功能关系，并确定结构、键合和反应性如何图案随着过渡金属和主族元素的变化而变化。 %%% 主族元素和过渡金属的基本相互作用对于化学、材料科学和催化来说是一个非常重要的话题。 主族/过渡金属合金具有有趣的电子和磁性，而主族元素化合物通常在商业催化过程中用作促进剂。