sp-Hybridized carbon as a building block in the synthesis of molecules and materials

sp-杂化碳作为分子和材料合成的构建模块

• 批准号: RGPIN-2017-05052
• 负责人: Tykwinski, Rik
• 金额: $ 10.13万
• 依托单位: University of Alberta
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2017
• 资助国家: 加拿大
• 起止时间: 2017-01-01 至 2018-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=632791
• 关键词: sp; Hybridized; carbon; building; block

This proposal outlines synthetic routes to carbon-rich molecules with defined structure using sp-hybridized carbon as a key building block. These molecules are designed to give answers to both fundamental and applied questions in chemistry, as well as physics and materials science. This program follows a “physical organic chemistry” approach: We examine detailed relationships between chemical structure and molecular reactivity/properties, commonly via thermal analyses, electrochemical methods, X-ray crystallography, as well as NMR, emission, and absorption spectroscopies (EPR, vibrational, and transient absorption spectroscopies are used via collaboration). Often, our molecules are designed to answer specific questions posed by collaborators in, for example, molecular electronics and solar energy capture. The proposed research program relies on four interrelated themes.

该提案概述了使用 sp 杂化碳作为关键构建块的具有明确结构的富碳分子的合成路线，这些分子旨在回答化学以及物理和材料科学中的基础和应用问题。遵循“物理有机化学”方法：我们通常通过热分析、电化学方法、X 射线晶体学以及 NMR、发射和吸收光谱（EPR、振动、通常，我们的分子旨在回答合作者提出的特定问题，例如分子电子学和太阳能捕获。