Group 13 Lewis acid appended transition metal complexes and actinide chemistry: unusual metal-ligand interactions and applications in catalysis

第 13 族路易斯酸附加过渡金属配合物和锕系化学：不寻常的金属-配体相互作用及其在催化中的应用

• 批准号: 298370-2010
• 负责人: Emslie, David
• 金额: $ 2.91万
• 依托单位: McMaster University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2014
• 资助国家: 加拿大
• 起止时间: 2014-01-01 至 2015-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=548317
• 关键词: Group; 13; Lewis; acid; appended

Research in the Emslie group is directed towards the synthesis and study of unusual or unique metal complexes which are of interest from both a fundamental perspective and for the development of improved catalysts and new types of stoichiometric and catalytic transformation. To this end, our NSERC funded research program is focused on the synthesis, properties and reactivity of: (1) Group 13 Lewis acid-appended late transition metal complexes, and (2) Non-carbocyclic thorium and uranium complexes.

Emslie 小组的研究方向是合成和研究不寻常或独特的金属配合物，这些配合物从基本角度以及改进催化剂的开发以及新型化学计量和催化转化方面都具有重要意义。为此，我们的 NSERC 资助的研究项目重点关注以下物质的合成、性质和反应性：(1) 第 13 族路易斯酸附加后过渡金属配合物，以及 (2) 非碳环钍和铀配合物。