Trace metal and metal isotope biogeochemistry

痕量金属和金属同位素生物地球化学

• 批准号: 355617-2008
• 负责人: Bergquist, Bridget
• 金额: $ 1.82万
• 依托单位: University of Toronto
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2013
• 资助国家: 加拿大
• 起止时间: 2013-01-01 至 2014-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=527838
• 关键词: Trace; metal; isotope; biogeochemistry

The primary aim of my research program is to increase our understanding of the biogeochemical cycles that are important for life on Earth through the use of trace metal and stable isotope geochemistry. Besides the inherent importance of metals in the environment (i.e., in their roles as nutrients or toxins), the chemistry of metals is often linked to, or plays a controlling role in, important environmental processes. Understanding metals in the environment is especially important in a changing world where human activities are perturbing many natural cycles and will have impacts on our food sources, health, and climate. New analytical advancements have opened the door for investigation of stable isotope fractionation of many metals. Isotopic signatures are powerful tools for identifying sources and sinks and for understanding biogeochemical cycling. My research program combines research on metal biogeochemistry with innovative studies of natural metal isotopic variations. The two primary objectives of my research program are (1) Metal Contaminants in the Environment and (2) The Marine Biogeochemistry of Trace Metals. The main focus of (1) will be the study of mercury. Mercury is a globally distributed and highly toxic pollutant. Much of the natural cycle of Hg is not well understood and new approaches are necessary to better track Hg sources and transformations in the environment. Dr. B.A. Bergquist recently demonstrated that Hg isotopes undergo unique isotopic fractionation that provides an indelible fingerprint for directly tracking and understanding Hg cycling in the environment. These findings pave the way for tracing the mobility and bioccumulation of the Hg in the environment. One of the goals of (2) will be to improve our understanding of the sources and biogeochemical cycling of iron in ocean. Iron is a vital micronutrient in the ocean and plays a fundamental role in climate change by influencing the carbon cycle of the ocean. Dr. Bergquist's research program combines both concentration and speciation studies of Fe with Fe isotopic signatures to gain insight into the sources and cycling of Fe in the ocean.

我的研究计划的主要目的是通过使用痕量金属和稳定的同位素地球化学来提高我们对生物地球化学周期对地球生命至关重要的理解。 除了金属在环境中的固有重要性（即，在其作为营养或毒素的作用中）外，金属的化学反应通常与重要的环境过程有关，或在重要的环境过程中起着控制作用。 在不断变化的世界中，人类活动正在扰乱许多自然周期，并将对我们的食物来源，健康和气候产生影响，了解环境中的金属尤为重要。 新的分析进步为研究许多金属的稳定同位素分馏打开了大门。 同位素特征是识别来源和水槽以及了解生物地球化学循环的强大工具。 我的研究计划将金属生物地球化学的研究与天然金属同位素变化的创新研究结合在一起。 我的研究计划的两个主要目标是（1）环境中的金属污染物和（2）痕量金属的海洋生物地球化学。 （1）的主要重点是汞研究。 汞是一种全球分布和剧毒污染物。 HG的大部分自然循环尚不清楚，并且需要新的方法来更好地跟踪HG来源和环境中的转化。 博士Bergquist最近证明，HG同位素经历独特的同位素分馏，该分级为直接跟踪和了解环境中的HG循环提供了不可磨灭的指纹。 这些发现为追踪环境中HG的迁移率和生物覆盖铺平了道路。 （2）的目标之一是提高我们对海洋中铁的来源和生物地球化学循环的理解。 铁是海洋中重要的微量营养素，通过影响海洋的碳循环在气候变化中起着基本作用。 Bergquist博士的研究计划结合了FE的集中度和FE同位素特征的集中和物种形成研究，以了解FE在海洋中的来源和循环。