The thermodynamics and statistical mechanics of nanoscale systems

纳米级系统的热力学和统计力学

• 批准号: 298398-2009
• 负责人: Bowles, Richard
• 金额: $ 2.19万
• 依托单位: University of Saskatchewan
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2012
• 资助国家: 加拿大
• 起止时间: 2012-01-01 至 2013-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=497875
• 关键词: thermodynamics; statistical; mechanics; nanoscale; systems

Nanoscale systems exhibit a rich variety of structures, quantum effects and phase transitions as a result of two primary effects: the increased importance of surface phenomena and the influence of fluctuations. We plan to develop computer simulation techniques and thermodynamic models that explicitly account for these features, then apply them to the study of phase transformations in nanosystems such as the freezing and melting of nanoparticles, the deliquescence of small atmospheric aerosols and capillarity condensation and cavitation in nanopores.

纳米级系统表现出各种各样的结构，量子效应和相变，这是两个主要效应的结果：表面现象的重要性和波动的影响。我们计划开发明确解释这些特征的计算机模拟技术和热力学模型，然后将它们应用于纳米系统中的相变，例如纳米颗粒的冷冻和熔化，小型大气气溶胶的跨层次和纳米果中的capillation和capillarity缩合和cabiation。