Reactivity Enhanced Low-Valent Alkaline Earth Metal Compounds

反应活性增强的低价碱土金属化合物

• 批准号: DP240101097
• 负责人: Prof Cameron Jones
• 金额: $ 37.4万
• 依托单位: Monash University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2024
• 资助国家: 澳大利亚
• 起止时间: 2024-01-01 至 2026-12-31
• 项目状态: 未结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP240101097
• 关键词: Reactivity; Enhanced; Low; Valent; Alkaline

The project aims to develop highly activated low oxidation state alkaline earth metal complexes as cheap and sustainable alternatives to toxic/expensive late transition metal complexes, that currently dominate the transformation of inert small molecule substrates into value-added organic chemicals. The project expects to generate major fundamental and applied advances in chemistry, using innovative synthetic and computational approaches, and a multidisciplinary collaborative team. Expected outcomes include building of academic and, later, industrial research capacity, knowledge, an international network, and a highly trained workforce. Success should see substantial economic, environmental and societal benefits flowing to Australia.

该项目旨在开发高度活化的低氧化状态碱土金属复合物作为廉价且可持续的替代品，用于有毒/昂贵的晚期过渡金属配合物，目前主导了惰性小分子底物向增值有机化学物质的转化。该项目预计将使用创新的合成和计算方法以及一个多学科的合作团队来产生化学方面的主要基本和应用进步。预期的结果包括建立学术和后来的工业研究能力，知识，国际网络和训练有素的劳动力。成功应该看到经济，环境和社会福利大量流向澳大利亚。