Investigation of Organic Nitrogen in Atmospheric Aerosols

大气气溶胶中有机氮的研究

基本信息

  • 批准号:
    NE/F01905X/1
  • 负责人:
  • 金额:
    $ 36.58万
  • 依托单位:
  • 依托单位国家:
    英国
  • 项目类别:
    Research Grant
  • 财政年份:
    2008
  • 资助国家:
    英国
  • 起止时间:
    2008 至 无数据
  • 项目状态:
    已结题

项目摘要

Organic nitrogen (ON) is ubiquitous in the atmosphere. Atmospheric particles typically have high concentrations of nitrogen and are a significant source of fixed nitrogen to the environment (though deposition processes), which may have an adverse impact on terrestrial and aquatic ecosystem. While the sources, formation and composition of oxygenated organics in the atmosphere have been extensively studied in recent years, ON has not received the same attention. Studies of atmospherically relevant processes (such as photo-chemical transformations) have been carried out on individual ON compounds but these studies are fundamentally limited since the bulk of ON in atmospheric particles is not characterized. The composition of ON within a particle may have an effect on its properties (such as hygroscopicity, toxicity and bio-availability) which will also change as the particle ages during long-range transport and may ultimately lead to the formation of humic-like substances. Studies have shown that when aqueous extracts of bulk ON from atmospheric aerosols were exposed to simulated sunlight and ozone, a significant portion of the ON was transformed into ammonium, nitrate and oxides of nitrogen. Atmospheric particles have been linked to increased mortality in the human population and a number of ON species are implicated in the toxicity of aerosols (e.g. nitrogentated polycyclic aromatic hydrocarbons, quinolines, nitroso-amines). The aim of this project is to build a novel, high resolution ON-Analyser capable of measuring the semi-volatile ON composition of atmospheric aerosols, for which there is currently very little known. It is based on a high resolution chromatographic technique (comprehensive two-dimensional gas chromatography - GCXGC) which is ideally suited to separating highly complex mixtures. This will be coupled to a highly selective nitrogen chemiluminescence detector, which provides a response for organic compounds containing nitrogen only. This removes interferences from the complex organic background found in aerosols. Aerosols will be samples onto filters and the ON content extracted using an Aerosol Thermal Desorption Injector. This novel instrument will be used to investigate the composition of ON species in aerosol in different environments, reflecting increasing photo-chemical age, from a polluted city centre roadside location (York) to a clean coastal rural site (Weybourne). Due to the complexity of the real atmosphere, linking the initial species emitted to the atmosphere to their reaction products in aerosol can be difficult. We will use the ON-Analyser to investigate the composition of ON in secondary organic aerosol formed in smog chamber simulations, allowing a direct link between pre-cursors and products. The outcomes of this project will increase our understanding of the composition, formation and transformation of organic nitrogen species in the atmosphere, providing valuable information across a range of disciplines including air quality, climate change and ecology.
有机氮(ON)在大气中无处不在。大气颗粒通常具有高浓度的氮,并且是对环境(尽管沉积过程)的固定氮的重要来源,这可能会对陆地和水生生态系统产生不利影响。尽管近年来已经对大气中有氧有机物的来源,形成和组成进行了广泛的研究,但尚未受到相同的关注。对大气相关的过程(例如光化学转化)的研究已在化合物上进行,但是这些研究在根本上受到限制,因为没有表征大部分大气颗粒中的大部分ON。粒子内部的组成可能会影响其特性(例如吸湿性,毒性和生物利用性),这也会随着粒子在远程运输过程中的年龄而变化,并最终可能导致腐殖质样物质的形成。研究表明,当将大气气溶胶的大量水提取物暴露于模拟的阳光和臭氧中时,将大部分ON转化为氮,硝酸盐和氮的氧化物。大气颗粒与人口的死亡率增加有关,许多ON物种与气溶胶的毒性有关(例如,硝化的多环芳烃,奎诺琳,硝基胺,硝基胺)。该项目的目的是建立一种新颖的,高分辨率的在菜鸟上,能够测量大气气溶胶组成的半挥发性,目前鲜为人知。它基于高分辨率色谱技术(综合二维气相色谱-GCXGC),它非常适合分离高度复杂的混合物。这将与高度选择性的氮化学发光探测器耦合,该检测器可为仅含有氮的有机化合物提供响应。这消除了气溶胶中发现的复杂有机背景的干扰。气溶胶将是过滤器上的样品,以及使用气溶胶热解吸器提取的含量。这种新颖的仪器将用于调查不同环境中气溶胶中物种的组成,反映了从污染的市中心路边(York)到干净的沿海乡村地点(Weybourne)的增长时代。由于真实气氛的复杂性,将发出的初始物种与气溶胶中的反应产物联系起来可能很困难。我们将使用跨分析仪研究在烟雾室模拟中形成的二次有机气溶胶中的ON组成,从而可以在前保车和产品之间直接联系。该项目的结果将增加我们对大气中有机氮物种的组成,形成和转化的理解,从而在包括空气质量,气候变化和生态学在内的一系列学科中提供宝贵的信息。

项目成果

期刊论文数量(10)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
The import and export of organic nitrogen species at a Scottish ombrotrophic peatland
  • DOI:
    10.5194/bg-13-2353-2016
  • 发表时间:
    2015-01
  • 期刊:
  • 影响因子:
    4.9
  • 作者:
    R. Mckenzie;M. Z. Ozel;J. Cape;J. Drewer;K. Dinsmore;E. Nemitz;Y. S. Tang;N. Dijk;M. Anderson;J. Hamilton;M. Sutton;M. Gallagher;U. Skiba
  • 通讯作者:
    R. Mckenzie;M. Z. Ozel;J. Cape;J. Drewer;K. Dinsmore;E. Nemitz;Y. S. Tang;N. Dijk;M. Anderson;J. Hamilton;M. Sutton;M. Gallagher;U. Skiba
Comparative study of comprehensive gas chromatography-nitrogen chemiluminescence detection and gas chromatography-ion trap-tandem mass spectrometry for determining nicotine and carcinogen organic nitrogen compounds in thirdhand tobacco smoke.
气相色谱-氮化学发光综合检测法与气相色谱-离子阱-串联质谱法测定三手烟草烟气中尼古丁和致癌有机氮化合物的对比研究
  • DOI:
    10.1016/j.chroma.2015.11.035
  • 发表时间:
    2015
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Ramírez N
  • 通讯作者:
    Ramírez N
Theoretical and Experimental Study on the Reaction of tert-Butylamine with OH Radicals in the Atmosphere.
  • DOI:
    10.1021/acs.jpca.8b01862
  • 发表时间:
    2018-04
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Wen Tan;Liang Zhu;T. Mikoviny;C. Nielsen;A. Wisthaler;Philipp Eichler;M. Müller;B. d'Anna;Naomi J. Farren;J. Hamilton;J. Pettersson;M. Hallquist;S. Antonsen;Y. Stenstrøm
  • 通讯作者:
    Wen Tan;Liang Zhu;T. Mikoviny;C. Nielsen;A. Wisthaler;Philipp Eichler;M. Müller;B. d'Anna;Naomi J. Farren;J. Hamilton;J. Pettersson;M. Hallquist;S. Antonsen;Y. Stenstrøm
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Jacqueline Hamilton其他文献

Testing a rapid assessment approach for estimating ecosystem service capacity in urban green alleys
  • DOI:
    10.1016/j.ufug.2024.128472
  • 发表时间:
    2024-09-01
  • 期刊:
  • 影响因子:
  • 作者:
    Marie C. Dade;Isabella C. Richmond;Jesse T. Rieb;Erin T.H. Crockett;Kayleigh Hutt-Taylor;Serena Sinno;Karina Benessaiah;Catherine Destrempes;Jacqueline Hamilton;Fatemeh Izadi;L. Emily Kroft;Lingshan Li;Michael A. Paulauskas;Klara J. Winkler;Elena M. Bennett;Carly D. Ziter
  • 通讯作者:
    Carly D. Ziter

Jacqueline Hamilton的其他文献

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{{ truncateString('Jacqueline Hamilton', 18)}}的其他基金

Hazard Identification Platform to Assess the Health Impacts from Indoor and Outdoor Air Pollutant Exposures, through Mechanistic Toxicology
通过机械毒理学评估室内和室外空气污染物暴露对健康的影响的危害识别平台
  • 批准号:
    NE/W002051/1
  • 财政年份:
    2021
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Investigating the large source of particulate mass from nitrophenols observed in Beijing during winter haze events
调查北京冬季雾霾事件期间观察到的硝基苯酚颗粒物的大来源
  • 批准号:
    NE/S006648/1
  • 财政年份:
    2019
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Using the complexity of secondary organic aerosols to understand their formation, ageing and transformation in three contrasting megacities
利用二次有机气溶胶的复杂性来了解它们在三个对比鲜明的大城市中的形成、老化和转变
  • 批准号:
    NE/S010467/1
  • 财政年份:
    2019
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Diffusion and Equilibration in Viscous Atmospheric Aerosol
粘性大气气溶胶的扩散和平衡
  • 批准号:
    NE/M002411/1
  • 财政年份:
    2015
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Com-Part: Combustion Particles in the Atmosphere: Properties, Transformations, Fate & Impacts
Com-Part:大气中的燃烧粒子:属性、转变、命运
  • 批准号:
    NE/K012959/1
  • 财政年份:
    2014
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Aerosol-Cloud Interaction - A Directed Programme to Reduce Uncertainty in Forcing through a Targeted Laboratory and Modelling Programme
气溶胶-云相互作用 - 通过有针对性的实验室和建模程序减少强迫不确定性的定向程序
  • 批准号:
    NE/I020040/1
  • 财政年份:
    2012
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Identification of missing organic reactivity in the urban troposphere
识别城市对流层中缺失的有机反应
  • 批准号:
    NE/J008532/1
  • 财政年份:
    2012
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Are glyoxal and methylglyoxal critical to the formation of a missing fraction of SOA (Secondary Organic Aerosol)?: (Pho-SOA).
乙二醛和甲基乙二醛对于 SOA(二次有机气溶胶)缺失部分的形成至关重要吗?:(Pho-SOA)。
  • 批准号:
    NE/H021221/1
  • 财政年份:
    2011
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Development of a lab on a chip comprehensive two-dimensional gas chromatography
综合二维气相色谱芯片实验室的研制
  • 批准号:
    NE/G000255/1
  • 财政年份:
    2008
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant
Chemical And Physical Structure Of The Lower Atmosphere Of The Tropical Eastern North Atlantic
热带北大西洋东部低层大气的化学和物理结构
  • 批准号:
    NE/E01111X/1
  • 财政年份:
    2007
  • 资助金额:
    $ 36.58万
  • 项目类别:
    Research Grant

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镍催化有机反应的基础研究
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枯草芽孢杆菌中硝酰基 (HNO) 的化学生物学
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